Sorption modelling on illite. Part II: Actinide sorption and linear free energy relationships

Geochimica et Cosmochimica Acta

Volumn 73, Issue 4, 2009, Pages 1004-1013

  Bradbury, M H ^a   Baeyens, B ^a  

^a PAUL SCHERRER INSTITUTE   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ACTINIDE; COMPLEXATION; ILLITE; ION EXCHANGE; MONTMORILLONITE; SORPTION; THERMODYNAMICS;

EID: 58549091282     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2008.11.016     Document Type: Article

References (30)

1. Baes C.F., and Mesmer R.E. The Hydrolysis of Cations (1976), Wiley, New York
2. Baeyens B., and Bradbury M.H. A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part I: titration and sorption measurements. J. Cont. Hydrol. 27 (1997) 199-222
3. Baeyens B., and Bradbury M.H. Cation exchange capacity measurements of illite using the sodium and cesium isotope dilution technique: effects of the index-cation, electrolyte concentration and competition: modeling. Clays Clay Miner. 52 (2004) 421-431
4. Bradbury M.H., and Baeyens B. A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part II: modelling. J. Cont. Hydrol. 27 (1997) 223-248
5. Bradbury M.H., and Baeyens B. Modelling the sorption of Zn and Ni on Ca-montmorillonite. Geochim. Cosmochim. Acta 63 (1999) 325-336
6. Bradbury M.H., and Baeyens B. Sorption of Eu on Na- and Ca-montmorillonites: experimental investigations and modelling with cation exchange and surface complexation. Geochim. Cosmochim. Acta 66 (2002) 2325-2334
7. Bradbury M. H. and Baeyens B. (2005) Modelling the sorption of Mn(II), Co(II), Ni(II), Zn(II), Cd(II), Eu(III), Am(III), Sn(IV), Th(IV), Np(V) and U(VI) on montmorillonite: linear free energy relationships and estimates of surface binding constants for some selected heavy metals and actinides. Geochim. Cosmochim. Acta 69, 875-892 and Erratum 69, 5391-5392.
8. Bradbury M.H., and Baeyens B. Sorption modelling on illite Part I: titration measurements and sorption of Ni(II), Co(II), Eu(III), and Sn(IV). Geochim. Cosmochim. Acta 73 (2009) 990-1003
9. Chapman N.B., and Shorter J. Advances in Linear Free Energy Relationships (1972), Plenum Press, London
10. Davies C.W. Ion Association (1962), Butterworths, London
11. Dzombak D.A., and Morel F.M.M. Surface Complexation Modeling: Hydrous Ferric Oxide (1990), Wiley-Interscience, New York
12. Gaines G.I., and Thomas H.C. Adsorption studies on clay minerals. II. A formulation of the thermodynamics of exchange adsorption. J. Chem. Phys. 21 (1953) 714-718
13. Gorgeon L. (1994) Contribution à la modélisation physico-chimique de la retention de radioéléments à vie longue par des matériaux argileux. Ph.D. thesis, Université Paris 6.
14. Grim R.E. Clay Mineralogy (1953), McGraw-Hill, New York
15. Hammett L.P. Physical Organic Chemistry (1940), McGraw-Hill, New York
16. Hummel W., Berner U., Curti E., Pearson F.J., and Thoenen T. Nagra/PSI Chemical Thermodynamic Data Base 01/01. Nagra Technical Report NTB 02-16, Nagra, Wettingen, Switzerland, and Universal Publishers/uPublish.com (2002), Parkland, Florida, USA
17. Larsson E. Die Dissoziationskonstanten von Aminium- und Silberdiaminionen und ein Zusammenhang zwischen ihnen. Z. Phys. Chem. A 169 (1934) 207-223
18. -. J. Soln. Chem. 32 (2003) 489-504
19. NEA (1992) Radionuclide Sorption from the Safety Evaluation Perspective. In Proceedings of an NEA Workshop, October 16-18, 1991, Interlaken, Switzerland. OECD Publications, Paris, France.
20. NEA (2001) Using Thermodynamic Sorption Models for Guiding Radioelement Distribution Coefficient (Kd) Investigations. OECD Publications, Paris, France.
21. NEA (2003) Update on the chemical thermodynamics of uranium, neptunium, plutonium, americium and technetium. In Chemical Thermodynamics, vol. 5 (ed. OECD Nuclear Energy Agency). Elsevier Science Publications BV. Amsterdam.
22. NEA (2005) Chemical thermodynamics of nickel. In Chemical Thermodynamics, vol. 6 (ed. OECD Nuclear Energy Agency). Elsevier Science Publications B.V., Amsterdam.
23. NEA (2005) NEA Sorption Project Phase II: interpretation and Prediction of Radionuclide Sorption onto Substrates Relevant for Radioactive Waste Disposal Using Thermodynamic Sorption Models. OECD/NEA, Paris.
24. Neck V., and Kim J.I. Solubility and hydrolysis of tetravalent actinides. Radiochim. Acta 89 (2001) 1-16
25. Perrin D.D., and Dempsey B. Buffers for pH and Metal Ion Control (1974), Chapman and Hall, London
26. Poinssot C., Baeyens B., and Bradbury M.H. Experimental and modelling studies of caesium sorption on illite. Geochim. Cosmochim. Acta 63 (1999) 3217-3227
27. 2+. J. Colloid Interface Sci. 55 (1976) 469-475
28. Taylor J.R. An Introduction to Error Analysis (1982), University Science Books, Mill Valey, USA
29. -. J. Soln. Chem. 31 (2002) 261-277
30. -. J. Soln. Chem. 31 (2003) 261-277