Cation exchange capacity measurements on illite using the sodium and cesium isotope dilution technique: Effects of the index cation, electrolyte concentration and competition: Modeling

Clays and Clay Minerals

Volumn 52, Issue 4, 2004, Pages 421-431

  Baeyens, Bart ^a   Bradbury, Michael H ^a  

^a PAUL SCHERRER INSTITUTE   (Switzerland)

Author keywords

Cation Exchange Capacity (CEC); Cesium; Illite du Puy; Isotopic dilution technique; Two site cation exchange model

Indexed keywords

CATION EXCHANGE CAPACITY; DILUTION;

CERIUM; ELECTROLYTES; ION EXCHANGE; ISOTOPES; POSITIVE IONS;

CLAY;

CATION EXCHANGE CAPACITY; CESIUM; CLAY MINERAL; ELECTROLYTE; ILLITE; SODIUM;

EID: 4444357504     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2004.0520403     Document Type: Article

References (35)

1. Baeyens, B. and Bradbury, M.H. (1997) A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part I: Titration and sorption measurements. Journal of Contaminant Hydrology, 27, 199-222.
2. Bolt, G.H., Sumner, M.E. and Kamphorst, A. (1963) A study of the equilibrium between three categories of potassium in an illitic soil. Soil Science Society of America Proceedings, 27, 294-299.
3. Bradbury, M.H. and Baeyens, B. (1994) Sorption by cation exchage. Incorporation of a cation exchange model into geochemical computer codes. PSI Bericht Nr. 94-07, Paul Scherrer Institut, Villigen PSI and NTB 94-11, Nagra, Wettingen, Switzerland.
4. Bradbury, M.H. and Baeyens, B. (1997) A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part II: Modelling. Journal of Contaminant Hydrology, 27, 223-248.
5. Bradbury, M.H. and Baeyens, B. (1998) A physico-chemical characterisation and geochemical modelling approach for determining porewater chemistries in argillaceous rocks. Geochimica et Cosmochimica Acta, 62, 783-795.
6. Bradbury, M.H. and Baeyens, B. (2000) A generalised sorption model for the concentration dependent uptake of Cs by argillaceous rock. Journal of Contaminant Hydrology, 42, 141-163.
7. Bradbury, M.H. and Baeyens, B. (2003) Porewater chemistry in compacted re-saturated MX-80 bentonite. Journal of Contaminant Hydrology, 61, 329-338.
8. Brouwer, E., Baeyens, B., Maes, A. and Cremers, A. (1983) Caesium and rubidium ion equilibria in illite clay. Journal of Physical Chemistry, 87, 1213-1219.
9. Bruggenwert, M.G.M. and Kamphorst, A. (1982) Survey of experimental information on cation exchange in soil systems. Pp. 141-203 in: Soil Chemistry B. Physico-Chemical Models (G.H. Bolt, editor). Elsevier, Amsterdam.
10. Cremers, A. (1968) Ionic movement in a colloidal environment. Postdoctoral thesis, University of Leuven, Leuven, Belgium, 205 pp.
11. Cremers, A. and Thomas, H.C. (1966) Self-diffusion in suspensions. Sodium in montmorillonite at equilibrium. Journal of Physical Chemistry, 70, 3229-3234.
12. Cremers, A., Elsen, A., De Preter, P. and Maes A. (1988) Quantitative analysis of radiocesium retention in soils. Nature, 335, 247-249.
13. Davies, C.W. (1962) Ion Association. Butterworths, London.
14. De Preter, P. (1990) Radiocesium retention in the aquatic, terrestrial and urban environment: a quantitative and unifying analysis. PhD thesis, University of Leuven, Leuven, Belgium, 93 pp.
15. Ebert, D.D. (1980) Alkali cation selectivity and fixation by clay minerals. Clays and Clay Minerals, 28, 161-172.
16. Gaines, G.I. and Thomas, H.C. (1953) Adsorption studies on clay minerals. II. A formulation of the thermodynamics of exchange adsorption. Journal of Physical Chemistry, 21, 714-718.
17. Gorgeon, L. (1994) Contribution à la modélisation physico-chimique de la retention de radioeléments à vie longue par des materiaux argileux. PhD thesis, Université Paris 6, France, 201 pp.
18. Goulding, K.W.T. and Talibudeen, O. (1980) Heterogeneity of cation-exchange sites for K-Ca exchange in aluminosilicates. Journal of Colloid and Interface Science, 78, 15-24.
19. Horseman, S.T., Higgo, J.J., Alexander, J. and Harrington, J.F. (1996) Water, gas and solute movement through argillaceous media. Report CC-96/1. Nuclear Energy Agency, OECD, Paris, France.
20. Jackson, M.L. (1968) Weathering of primary and secondary minerals in soils. Transactions of the International Society of Soil Science, 4, 281-292.
21. Jenne, E.A. (1977) Trace element sorption by sediments and soils: Sites and processes. Pp. 425-553 in: Molybdenum in the Environment, Vol. 2 (W. Chappel and K. Peterson, editors). Dekker, New York.
22. 133Cs NMR study of cation adsorption on mineral surfaces: Local environments, dynamics, and effects of mixed cations. Geochimica et Cosmochimica Acta, 61, 5199-5208.
23. 133Cs NMR study of cesium on the surfaces of kaolinite and illite. Geochimica et Cosmochimica Acta, 60, 4059-4074.
24. Maes, A. and Cremers, A. (1975) Cation-exchange hysteresis in montmorillonite: A pH-dependent effect. Soil Science, 119, 198-202.
25. Maes, A. and Cremers, A. (1977) Charge density effects in ion exchange. Part 1. Heterovalent exchange equilibria. Journal of the Chemical Society, Faraday Transactions 1, 73, 1807-1814.
26. Maes, A. and Cremers, A. (1986) Europium sorption on a clay sediment: sulphate and ionic strength effects. Pp. 103-110 in: Application of Distribution Coefficients to Radiological Assessment Models. (T.H. Sibley and C. Myttenaere, editors). Elsevier, Amsterdam.
27. Maes, A., Peigneur, P. and Cremers, A. (1976) Thermodynamics of transition metal ion exchange in montmorillonite. Proceedings of the International Clay Conference, Mexico City, pp. 319-329.
28. NAGRA (2002) Project Opalinus Clay. Safety Report. Demonstration of disposal feasibility for spent fuel, vitrified high-level waste and long-lived intermediate-level waste (Entsorgungsnachweis). NTB 02-05, Nagra, Wettingen, Switzerland.
29. Poinssot, C., Baeyens, B. and Bradbury, M.H. (1999a) Experimental studies of Cs, Sr, Ni, and Eu sorption on Naillite and the modelling of Cs sorption. PSI Bericht Nr. 99-06, Paul Scherrer Institut, Villigen PSI and NTB 99-04, Nagra, Wettingen, Switzerland.
30. Poinssot, C., Baeyens, B. and Bradbury, M.H. (1999b) Experimental and modelling studies of caesium sorption on illite. Geochimica et Cosmochimica Acta, 63, 3217-3227.
31. Sawhney, B.L. (1970) Potassium and cesium ion selectivity in relation to clay mineral structure. Clays and Clay Minerals, 18, 47-52.
32. Sawhney, B.L. (1972) Selective adsorption and fixation of cations by clay minerals: A review. Clays and Clay Minerals, 20, 93-100.
33. Sposito, G., Holtzclaw, K.M., Charlet, L., Jouany, C. and Page, A.L. (1983) Sodium-calcium and sodium-magnesium exchange on Wyoming Bentonite in Perchlorate and chloride background ionic media. Journal of the Soil Science Society of America, 47, 51-56.
34. Tamura, T. and Jacobs, D.G. (1960) Structural implications in cesium sorption. Health Physics, 2, 391-398.
35. Van Bladel, R. and Menzel, R, (1969) A thermodynamic study of sodium-strontium exchange on Wyoming bentonite. Proceedings of the International Clay Conference, Tokyo, pp. 619-634.