Hydrolysis of Protactinium(V). II. Equilibrium Constants at 40 and 60°C: A Solvent Extraction Study with TTA in the Aqueous System Pa(V)/H 2O/H+/Na+/ClO4-

Journal of Solution Chemistry

Volumn 32, Issue 6, 2003, Pages 489-504

  Le Naour, C ^a   Trubert, D ^a   Jaussaud, C ^a  

^a CENTRE DE CALCUL DE L INSTITUT NATIONAL DE PHYSIQUE NUCLEAIRE ET DE PHYSIQUE DES PARTICULES   (France)

Author keywords

Hydrolysis; Ionic strength; NaClO4 solution; Protactinium; SIT modeling; Solution thermodynamics; Solvent extraction; TTA

Indexed keywords

CHELATING AGENT; CHLORATE; KETONE DERIVATIVE; PERCHLORATE; PROTACTINIUM; PROTON; SODIUM ION; TOLUENE; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL MODEL; EQUILIBRIUM CONSTANT; HYDROLYSIS; IONIC STRENGTH; SOLVENT EXTRACTION; TEMPERATURE;

EID: 0347555453     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1025357731301     Document Type: Article

References (18)

1. R. Guillaumont, Ph.D. Thesis (in French), Faculté des Sciences, Université de Paris, France, No. 5528 (1966).
2. R. Guillaumont, G. Bouissières, and R. Muxart, Actinides Rev. 1, 135 (1968).
3. J. Fuger, I. L. Khodakovsky, E. I. Sergeyeva, and J. D. Navratil, The Chemical Thermodynamics of Actinide Elements and Compounds: Part 12. The Actinide Aqueous Inorganic Complexes (IAEA, Vienna, 1992).
4. D. Trubert, C. Le Naour, and C. Jaussaud, J. Solution Chem. 31, 261 (2002).
5. C. Jaussaud, Ph.D. Thesis (in French), Université Paris XI-Orsay, France (2003).
6. J. Rydberg, Arkiv. Kemi 8, 101 (1955).
7. O. Söhnel and P. Novotny, Densities of Aqueous Solutions of Inorganic Substances (Elsevier, Amsterdam, 1985).
8. R. Guillaumont and G. Bouissières, Bull. Soc. Chim. Fr., p. 2098 (1965).
9. S. Suzuki and Y. Inoue, Bull. Chem. Soc. Jpn. 39, 1705 (1966).
10. R. T. Kolarich, V. A. Ryan, and R. P. Shuman, J. Inorg. Nucl. Chem. 29, 783 (1967).
11. A. T. Kandil, A. S. Abdel Gawad, and A. Ramadan, Radiochim. Acta 27, 39 (1980)
12. H. B. Maghrawy, C. Gircis, and A. S. Abdel-Gawad, J. Radioanal. Nucl. Chem. 81, 5 (1984).
13. R. Muxart, R. Guillaumont, and G. Bouiśsières, Actinides Rev. 1, 223 (1969).
14. J. Rydberg, C. Musikas, and G. R. Choppin, Principles and Practices of Solvent Extraction (Marcel Dekker, New York, 1992).
15. R. Guillaumont, Bull. Soc. Chim. Fr., p. 132 (1965).
16. I. Grenthe and I. Puigdomenech, eds., Modelling in Aquatic Chemistry (OECD/NEA, Paris, 1997).
17. R. J. Lemire, J. Fuger, H. Nitsche, P. Potter, M. H. Rand, J. Rydberg, K. Spahiu, J. C. Sullivan, W. J. Ullman, P. Vitorge, and H. Wanner, Chemical Thermodynamics of Neptunium and Plutonium (OECD/NEA, Paris, 2001).
18. E. Giffaut, Ph.D. Thesis (in French), Université Paris XI-Orsay, France (1994).