Synthetic studies directed toward guianolides: an organoiron route to the 5,7,5 tricyclic ring system

Tetrahedron Letters

Volumn 50, Issue 9, 2009, Pages 1023-1025

  Gone, Jayapal Reddy ^a   Wallock, Nathaniel J ^a   Lindeman, Sergey ^a   Donaldson, William A ^a  

^a Marquette University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNYL GROUP; CYCLOPROPANE DERIVATIVE; GAMMA LACTONE DERIVATIVE; GRIGNARD REAGENT; HETEROCYCLIC COMPOUND; IRON DERIVATIVE; SESQUITERPENE DERIVATIVE; VINYL DERIVATIVE;

ARTICLE; COPE REARRANGEMENT; CRYSTAL STRUCTURE; DIASTEREOISOMER; OXIDATION; REACTION ANALYSIS; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 58149501802     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.12.051     Document Type: Article

References (28)

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21. 3) δ 0.81 (d, J = 9.0 Hz, 3H), 1.08 and 1.09 (2 × s, 9H total), 1.52-1.74 (m, 2H), 1.87-1.99 (m, 1H), 2.22-2.3.11 (m, 1H), 2.32-2.49 (m, 2H), 2.86-2.96 and 3.10-3.20 and 3.28-3.43 (m, 2H total), 4.06-4.19 and 4.32-4.39 (2 × m, 1H total), 5.24-5.50 (m, 2H), 5.81-5.92 (m, 1H), 7.35-7.49 (m, 6H), 7.65-7.76 (m, 4H).
22. A similar selective reduction has been reported:. Davies H.M.L., and Doan B.D. J. Org. Chem. 63 (1998) 657-660
23. +) m/z 450.2804).
24. +) m/z 228.1576).
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28. +) m/z 223.1334).