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Volumn 9, Issue 18, 2008, Pages 2722-2730

Temperature and concentration effects on the solvophobic solvation of methane in aqueous salt solutions

Author keywords

Dynamics; Electrostriction effects; Methane; Molecular dynamics; Solvation; Thermodynamics

Indexed keywords

DYNAMICS; ELECTROSTRICTION; FREE ENERGY; INFORMATION THEORY; MOLECULAR DYNAMICS; SODIUM COMPOUNDS; SOLVATION; SUPERCOOLING; TEMPERATURE DISTRIBUTION; THERMODYNAMICS;

EID: 58049158913     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200800544     Document Type: Article
Times cited : (13)

References (67)
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    • Fitted excess chemical potential μexT, μ0+μ1 T+μ2T2+ μ3T3 of methane in water and aqueous salt solution. Water: μ0, 4.89×101 kJ mol -1, μ1, 3.76 × 10-1 kJ mol -1, μ1, μ2, 7.46×10-4 kJmol-1K-2, μ, 4.74× 10-7 kJ mol -1K-3. 3.85 mol% NaCl solution: μ0, 4.48×101 kJ mol-1, μ1, 3.76×10-1 kJmol-1K-1, μ2, 7.94×10-1 kJmol-1K-2, μ3= 5.61× 10-7 kJ mol-1K-3
    • -3.
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    • w·Cl ≤ 0.62 nm). The enclosed by all of these spheres Is labeled shell. The outside these spheres is referenced to as bulk.
    • w·Cl ≤ 0.62 nm). The volume enclosed by all of these spheres Is labeled "shell". The volume outside these spheres is referenced to as "bulk".


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.