Nonideal gas solvation thermodynamics

Journal of Chemical Physics

Volumn 126, Issue 10, 2007, Pages

  Ben Amotz, Dor ^a   Widom, B ^b  

^a PURDUE UNIVERSITY   (United States)

^b Department of Molecular Biology and Genetics   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NONIDEAL GAS SOLVATION; NONIDEAL SOLVENTS; SOLVENT REORGANIZATION; THERMODYNAMIC FUNCTIONS;

EQUATIONS OF STATE OF GASES; FUNCTIONS; POTENTIAL ENERGY FUNCTIONS; SOLVATION; SOLVENTS; SPECIFIC HEAT; THERMODYNAMIC PROPERTIES;

GAS DYNAMICS;

EID: 33947307623     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2464081     Document Type: Article

References (20)

1. J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids (Wiley, New York, 1964).
2. R. H. Fowler and E. A. Guggenheim, Statistical Thermodynamics (Cambridge University Press, London, 1939).
3. T. L. Hill, An Introduction to Statistical Thermodynamics (Dover, New York, 1960).
4. J. E. Mayer, J. Phys. Chem. 43, 71 (1939).
5. K. Fuchs, Proc. R. Soc. London, Ser. A 179, 0408 (1942).
6. D. Ben-Amotz, F. Rainery, and G. Stell, J. Phys. Chem. B 1089-5647 10.1021/jp045090z 109, 6866 (2005).
7. D. Ben-Amotz, J. Chem. Phys. 0021-9606 10.1063/1.2121648 123, 184504 (2005).
8. D. Ben-Amotz and B. Widom, J. Phys. Chem. B 110, 19839 (2006).
9. B. Widom, Science 157, 375 (1967).
10. B. Widom, J. Phys. Chem. 0022-3654 10.1021/j100395a005 86, 869 (1982).
11. A. Ben-Naim, Solvation Thermodynamics (Plenum, New York, 1987).
12. H. N. W. Lekkerkerker and B. Widom, Physica A 285, 483 (2000).
13. A. V. Plyasunov and E. L. Shock, J. Chem. Eng. Data 0021-9568 10.1021/je034046u 48, 808 (2003); O. Akin-Ojo, A. H. Harvey, and K. Szalewicz, J. Chem. Phys. 0021-9606 125, 014314 (2006); L. Meng and Y. Y. Duan, Fluid Phase Equilib. 0378-3812 10.1016/j.fluid.2005.10.007 238, 229 (2005); C. Tsonopoulos, AIChE J. 20, 263 (1974).
14. A. V. Plyasunov and E. L. Shock, J. Chem. Eng. Data 0021-9568 10.1021/je034046u 48, 808 (2003); O. Akin-Ojo, A. H. Harvey, and K. Szalewicz, J. Chem. Phys. 0021-9606 125, 014314 (2006); L. Meng and Y. Y. Duan, Fluid Phase Equilib. 0378-3812 10.1016/j.fluid.2005.10.007 238, 229 (2005); C. Tsonopoulos, AIChE J. 20, 263 (1974).
15. A. V. Plyasunov and E. L. Shock, J. Chem. Eng. Data 0021-9568 10.1021/je034046u 48, 808 (2003); O. Akin-Ojo, A. H. Harvey, and K. Szalewicz, J. Chem. Phys. 0021-9606 125, 014314 (2006); L. Meng and Y. Y. Duan, Fluid Phase Equilib. 0378-3812 10.1016/j.fluid.2005.10.007 238, 229 (2005); C. Tsonopoulos, AIChE J. 20, 263 (1974).
16. A. V. Plyasunov and E. L. Shock, J. Chem. Eng. Data 0021-9568 10.1021/je034046u 48, 808 (2003); O. Akin-Ojo, A. H. Harvey, and K. Szalewicz, J. Chem. Phys. 0021-9606 125, 014314 (2006); L. Meng and Y. Y. Duan, Fluid Phase Equilib. 0378-3812 10.1016/j.fluid.2005.10.007 238, 229 (2005); C. Tsonopoulos, AIChE J. 20, 263 (1974).
17. E. W. Lemmon, A. P. Perkins, M. O. McLinden, and D. G. Friend, NIST Standard Reference Database 12, Version 5.0 (2000).
18. E. W. Lemmon, M. O. McLinden, and M. L. Huber, NIST Standard Reference Database 23, Version 7.0 (2002).
19. D. R. Lide, Handbook of Chemistry and Physics, 77th ed. (CRC Press, Boca Raton, 1996).
20. Notice that the last equality in Eq. implicitly identifies Δ μrxn c i μi0 as the chemical potential change associated with the complete conversion of reactants to products, all at the same number density, ρ c = ρ 0 =1 (in whatever units are used to measure ρ c and qcI).