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Volumn 47, Issue 23, 2008, Pages 10816-10824

Probing the electronic communication of the isocyanide bridge through the luminescence properties of the d9-d9 [ClPt(μ-dppm) 2Pt(C≡N-PCP)]+ and A-frame [ClPd(μ-dppm) 2(μ-C=N-PCP)PdCl] complexes

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EID: 57949098460     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800811j     Document Type: Article
Times cited : (18)

References (73)
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    • Frisch, M. J.; Tracks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A.; Vreven, J. T.; Kudin, K. N., Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B., Cossi, M., Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O. Nakai, H Klene, M. Li, X. Knox, J. E. Hratchian, H. P.; Cross, J. B. Adamo, C. Jaramillo, J. Gomperts, R. Stratmann, R. E. Yazyev, O. Austin, A. J. Cammi, R. Pomelli, C. Ochterski, J. W. Ayala, P. Y. Morokuma, K. Voth, G. A. Salvador, P. Dannenberg, J. J. Zakrzewski, V. G. Dapprich, S. Daniels, A. D. Strain, M. C. Farkas, O. Malick, D. K. Rabuck, A. D. Raghavachari, K. Foresman, J. B. Ortiz, J. V. Cui, Q. Baboul, A. G. Clifford, S. Cioslowski, J. Stefanov, B. B. Liu, G. Liashenko, A. Piskorz, P. Komaromi, I. Martin, R. L. Fox, D. J. Keith, T. Al-Laham, M. A. Peng, C. Y. Nanayakkara, A. Challacombe, M. Gill, P. M. W. Johnson, B. Chen, W. Wong, M. W. Gonzalez, C. Pople, J. A. Gaussian 03, Revision C.02; Gaussian,Inc: Wallingford CT, 2004.
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    • We have recently prepared the A-frame complex [ClPd(μ-dppm) 2(μ-C=N-C6H4Pri)PdCl, whose four 31P nuclei give rise to a sharp singlet at δ 17.8, proofing the fluxionality of this type of compounds
    • 31P nuclei give rise to a sharp singlet at δ 17.8, proofing the fluxionality of this type of compounds.
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    • An AA′BB′ pattern was observed for the 31P{ 1H} NMR spectrum of [ClPd(μ-dppm)2(μ-N=N-C 6H4OCH3)PdCl]BF4. See: Neve, F, Longeri, M, Ghedini, M, Crispini, A. Inorg. Chim. Acta 1993, 205, 15-22
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    • (a) Bazan, G. C.; Jr, W. J. O.; Lachicotte, R. J.; Tretiak, S.; Chernyak, V.; Mukamel, S. J. Am. Chem. Soc. 1998, 120, 9188-9204.
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    • The ethynyl linker (-C≡C-) provides polymers of better conjugation. Recent papers by our group show clear evidence for conjugation and good communication across the polymer backbone. See: Gagnon, K.; Mohammed Aly, S.; Brisach-Wittmeyer, A.; Bellows, D.; Berube, J.-F.; Caron, L.; Abd-El-Aziz, A. S.; Fortin, D.; Harvey, P. D. Organometallics 2008, 27, 2201-2214, for example.
    • The ethynyl linker (-C≡C-) provides polymers of better conjugation. Recent papers by our group show clear evidence for conjugation and good communication across the polymer backbone. See: Gagnon, K.; Mohammed Aly, S.; Brisach-Wittmeyer, A.; Bellows, D.; Berube, J.-F.; Caron, L.; Abd-El-Aziz, A. S.; Fortin, D.; Harvey, P. D. Organometallics 2008, 27, 2201-2214, for example.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.