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The ethynyl linker (-C≡C-) provides polymers of better conjugation. Recent papers by our group show clear evidence for conjugation and good communication across the polymer backbone. See: Gagnon, K.; Mohammed Aly, S.; Brisach-Wittmeyer, A.; Bellows, D.; Berube, J.-F.; Caron, L.; Abd-El-Aziz, A. S.; Fortin, D.; Harvey, P. D. Organometallics 2008, 27, 2201-2214, for example.
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The ethynyl linker (-C≡C-) provides polymers of better conjugation. Recent papers by our group show clear evidence for conjugation and good communication across the polymer backbone. See: Gagnon, K.; Mohammed Aly, S.; Brisach-Wittmeyer, A.; Bellows, D.; Berube, J.-F.; Caron, L.; Abd-El-Aziz, A. S.; Fortin, D.; Harvey, P. D. Organometallics 2008, 27, 2201-2214, for example.
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