Chemical degradation of proton conducting perflurosulfonic acid ionomer membranes studied by solid-state nuclear magnetic resonance spectroscopy

Journal of Power Sources

Volumn 186, Issue 2, 2009, Pages 334-338

  Ghassemzadeh, L ^a,b   Marrony, M ^c   Barrera, R ^d   Kreuer, K D ^a   Maier, J ^a   Muller K ^b  

^a MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

^b UNIVERSITY OF STUTTGART   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^d Edison Spa   (Italy)

Author keywords

Fuel cell; Hyflon Ion; In situ degradation test; Nafion; Solid state NMR

Indexed keywords

CELL MEMBRANES; CONDUCTING POLYMERS; DEGRADATION; ELECTRIC BATTERIES; ELECTROCHEMISTRY; FLEXIBLE STRUCTURES; FUEL CELLS; FUNCTIONAL POLYMERS; IONS; MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE; PHOTODEGRADATION; PHOTORESISTS; POLYMERS; SOLID OXIDE FUEL CELLS (SOFC); SOLID STATE PHYSICS;

CHEMICAL DEGRADATIONS; DEGRADATION PROCESSES; DEGREE OF DEGRADATIONS; HYFLON ION; IN SITU DEGRADATION TEST; IONOMER MEMBRANES; MEMBRANE STRUCTURES; MEMBRANE THICKNESSES; NAFION; NMR SIGNALS; NMR SPECTROSCOPIES; PERFLUORINATED POLYMERS; POLYMER SIDE CHAINS; PROTON CONDUCTING; SOLID-STATE NMR; SPECTROSCOPIC TECHNIQUES; STRUCTURAL CHANGES;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 57949083312     PISSN: 03787753     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jpowsour.2008.10.004     Document Type: Article

References (45)

1. Sethuraman V.A., Weidner J.W., Haug A.T., and Protsailo L.V. Journal of the Electrochemical Society 155 (2008) B119-B124
2. Inaba M., Kinumoto T., Kiriake M., Umebayashi R., Tasaka A., and Ogumi Z. Electrochimica Acta 51 (2006) 5746-5753
3. Knights S.D. Journal of Power Sources 127 (2004) 127-134
4. Endoh E. Electrochemical and Solid State Letters 7 (2004) A209-A211
5. Shibahara Y., Akiyama Y., Izumi Y., Nishijima S., Honda Y., Kimura N., Tagawa S., and Isoyama G. Journal of Polymer Science Part B: Polymer Physics 46 (2008) 1-7
6. Chen C., Levitin G., Hess D.W., and Fuller T.F. Journal of Power Sources 169 (2007) 288-295
7. Bosnjakovic A., Kadirov M.K., and Schlick S. Research on Chemical Intermediates 33 (2007) 677-687
8. Danilczuk M., Bosnjakovic A., Kadirov M.K., and Schlick S. Journal of Power Sources 172 (2007) 78-82
9. Kinumoto T., Inaba M., Nakayama Y., Ogata K., Umebayashi R., Tasaka A., Iriyama Y., Abe T., and Ogumi Z. Journal of Power Sources 158 (2006) 1222-1228
10. Bosnjakovic A., and Schlick S. Journal of Physical Chemistry B 108 (2004) 4332-4337
11. Pozio A., Silva R.F., De Francesco M., and Giorgi L. Electrochimica Acta 48 (2003) 1543-1549
12. Okada T., Ayato Y., Satou H., Yuasa M., and Sekine I. Journal of Physical Chemistry B 105 (2001) 6980-6986
13. Bauer R., Waldner G., Fallmann H., Hager S., Klare M., Krutzler T., Malato S., and Maletzky P. Catalysis Today 53 (1999) 131-144
14. Mittal V.O., Kunz H.R., and Fenton J.M. Journal of the Electrochemical Society 154 (2007) B652-B656
15. Aoki M., Uchida H., and Watanabe M. Electrochemistry Communications 8 (2006) 1509-1513
16. Yu J.R., Matsuura T., Yoshikawa Y., Islam M.N., and Hori M. Electrochemical and Solid State Letters 8 (2005) A156-A158
17. Aoki M., Uchida H., and Watanabe M. Electrochemistry Communications 7 (2005) 1434-1438
18. Mittal V.O., Kunz H.R., and Fenton J.M. Journal of the Electrochemical Society 153 (2006) A1755-A1759
19. Yu J.R., Yi B.L., Xing D.M., Liu F.Q., Shao Z.G., and Fu Y.Z. Physical Chemistry Chemical Physics 5 (2003) 611-615
20. Merlo L., Ghielmi A., Cirillo L., Gebert M., and Arcella V. Journal of Power Sources 171 (2007) 140-147
21. Panchenko A. Journal of Membrane Science 278 (2006) 269-278
22. Mitov S., Vogel B., Roduner E., Zhang H., Zhu X., Gogel V., Jorissen L., Hein M., Xing D., Schonberger F., and Kerres J. Fuel Cells 6 (2006) 413-424
23. Kadirov M.K., Bosnjakovic A., and Schlick S. Journal of Physical Chemistry B 109 (2005) 7664-7670
24. Tang H.L., Shen P.K., Jiang S.P., Fang W., and Mu P. Journal of Power Sources 170 (2007) 85-92
25. Qiao J.L., Saito M., Hayamizu K., and Okada T. Journal of the Electrochemical Society 153 (2006) A967-A974
26. Hubner G., and Roduner E. Journal of Materials Chemistry 9 (1999) 409-418
27. Curtin D.E., Lousenberg R.D., Henry T.J., Tangeman P.C., and Tisack M.E. Journal of Power Sources 131 (2004) 41-48
28. LaConti A., Hamdan M., and McDonald R. Handbook of Fuel Cells: Fundamentals, Technology, and Applications (2003) pp. 647-662
29. Zhou C., Guerra M.A., Qiu Z.M., Zawodzinski T.A., and Schiraldi D.A. Macromolecules 40 (2007) 8695-8707
30. Xie T., and Hayden C.A. Polymer 48 (2007) 5497-5506
31. Liu W., Ruth K., and Rusch G. Journal of New Materials for Electrochemical Systems 4 (2001) 227-232
32. Rhoades D.W., Hassan M.K., Osborn S.J., Moore R.B., and Mauritz K.A. Journal of Power Sources 172 (2007) 72-77
33. Panchenko A., Dilger H., Moller E., Sixt T., and Roduner E. Journal of Power Sources 127 (2004) 325-330
34. Lund A., Macomber L.D., Danilczuk M., Stevens J.E., and Schlick S. Journal of Physical Chemistry B 111 (2007) 9484-9491
35. Panchenko A., Dilger H., Kerres J., Hein M., Ullrich A., Kaz T., and Roduner E. Physical Chemistry Chemical Physics 6 (2004) 2891-2894
36. Huang C.D., Tan K.S., Lin H.Y., and Tan K.L. Chemical Physics Letters 371 (2003) 80-85
37. Healy J., Hayden C., Xie T., Olson K., Waldo R., Brundage A., Gasteiger H., and Abbott J. Fuel Cells 5 (2005) 302-308
38. Mauritz K.A., and Moore R.B. Chemical Reviews 104 (2004) 4535-4585
39. Merlo L., Ghielmi A., Cirillo L., Gebert M., and Arcella V. Separation Science and Technology 42 (2007) 2891-2908
40. Liu S.F., and Schmidt-Rohr K. Macromolecules 34 (2001) 8416-8418
41. Marrony M., Barrera R., Quenet S., Ginocchio S., Montelatici L., and Aslanides A. Journal of Power Sources 182 (2008) 469-475
42. Kreuer K.D., Schuster M., Obliers B., Diat O., Traub U., Fuchs A., Klock U., Paddison S.J., and Maier J. Journal of Power Sources 178 (2008) 499-509
43. Chen Q., and Schmidt-Rohr K. Macromolecules 37 (2004) 5995-6003
44. Kreuer K.D., Paddison S.J., Spohr E., and Schuster M. Chemical Reviews 104 (2004) 4637-4678
45. L. Ghassemzadeh, K.D. Kreuer, J. Maier, K. Müller, in preparation.