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Perchlorates are known as oxidizers and explosives. Although the authors found 5 is safe under the reaction conditions, safety precautions are necessary.
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Perchlorates are known as oxidizers and explosives. Although the authors found 5 is safe under the reaction conditions, safety precautions are necessary.
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24
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0344495971
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57449120407
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3-acetonitrile which might be attributed to intramolecular hydrogen bonding; nevertheless, the chemical shifts still showed an obvious difference from those of authentic 1. Peak-assignments for α and β-Hs were based on the HH COSY NMR data. See Figure S30 in the Suppporting Information.
-
3-acetonitrile which might be attributed to intramolecular hydrogen bonding; nevertheless, the chemical shifts still showed an obvious difference from those of authentic 1. Peak-assignments for α and β-Hs were based on the HH COSY NMR data. See Figure S30 in the Suppporting Information.
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27
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57449093917
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See the Supporting Information
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See the Supporting Information.
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28
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57449106976
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The structure of 6 was confirmed by X-ray crystallography. See the Supporting Information.
-
The structure of 6 was confirmed by X-ray crystallography. See the Supporting Information.
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30
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57449097719
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Aldehydes give less than 10% yields of products
-
Aldehydes give less than 10% yields of products.
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31
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0004042577
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