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We additionally formed two new films of amine-containing polymers, poly(aminoethyl methacrylate, PAEMA) and poly(2-(tert-butylamino) ethyl methacrylate, PTBAEMA, The former contained primary amines and the later contained secondary amines. The IR and SEM characterizations indicated that these two polymeric films also induced the TiO2 deposition, and the resulting films were relatively uniform see Figures S5 and S6 in the Supporting Information for the SEM micrographs, The only quaternary amine-containing polymer, q-PDMAEMA, led to uncontrollable TiO2 deposition. These results indicated that the chemical nature of positive charges would be more important than methylation in the control of TiO2 deposition. In the case of primary, secondary, and tertiary amines, positive charges, generated by protonation, would not be developed in the entire films of polymers. In contrast, permanent positive charges, present on q-PDMAEMA, could induce TiO2 form
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2 formation along the whole layer of the q-PDMAEMA film in a somewhat uncontrollable manner.
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92
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0033877980
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R. R. Shah, D. Merreceyes, M. Husemann, I. Rees, N. L. Abbott, C. J. Hawker, J. L. Hedrick, Macromolecules 2000, 33, 597.
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(2000)
Macromolecules
, vol.33
, pp. 597
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Shah, R.R.1
Merreceyes, D.2
Husemann, M.3
Rees, I.4
Abbott, N.L.5
Hawker, C.J.6
Hedrick, J.L.7
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