Synthesis and X-ray powder diffraction characterization of tetra- and hexa-imidazole complexes of magnesium(II)

Powder Diffraction

Volumn 23, Issue 4, 2008, Pages 286-291

  Masciocchi, Norberto ^a   Garlaschelli, Luigi ^b   Peli, Giulia ^a  

^a UNIVERSITY OF INSUBRIA   (Italy)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

Imidazole; Magnesium; Powder diffraction; Rietveld refinement

Indexed keywords

CRYSTAL AND MOLECULAR STRUCTURE; IMIDAZOLE; MONOCLINIC SYSTEMS; OCTAHEDRALLY COORDINATED; POWDER DIFFRACTION; RIETVELD REFINEMENT METHOD; SPECTROSCOPIC CHARACTERIZATION; THERMO-GRAVIMETRIC;

COORDINATION REACTIONS; DIFFRACTION; MAGNESIUM; MAGNESIUM POWDER; PLANTS (BOTANY); RIETVELD REFINEMENT; SIMULATED ANNEALING; SYNTHESIS (CHEMICAL); X RAY POWDER DIFFRACTION;

CHLORINE COMPOUNDS;

EID: 57249105381     PISSN: 08857156     EISSN: 19457413     Source Type: Journal    
DOI: 10.1154/1.3005369     Document Type: Article

References (15)

1. Cingolani, A., Galli, S., Masciocchi, N., Pandolfo, L., Pettinari, C., and Sironi, A. (2005). " Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers.," J. Am. Chem. Soc. 127, 6144-6145.
2. Galli, S., Masciocchi, N., Tagliabue, G., Sironi, A., Barea, E., Salas, J. M., Mendez, L., Domingo, M., Perez-Mendoza, M., and Navarro, J. A. R. (2008). " Polymorphic coordination networks responsive to C O2, moisture and thermal stimuli: porous cobalt(II) and zinc(II) fluoropyrimidinolates.," Chem.-Eur. J., in the press.
3. Gong, Y., Hu, C., Li, H., Pan, W., Niu, X., and Pu, Z. (2005). " Synthesis and crystal structure of two novel nickel (imidazole) complexes having hydrogen-bonded networks.," J. Mol. Struct. 740, 153-158.
4. Kahn, O. and Codjovi, E. (1996). " Iron(II)-1,2,4-triazole spin transition molecular materials.," Philos. Trans. R. Soc. London, Ser. A 354, 359-379.
5. Masciocchi, N., Ardizzoia, G. A., LaMonica, G., Maspero, A., and Sironi, A. (1998). " Unique formation of a crystal phase containing cyclic oligomers and helical polymers of the same monomeric fragment.," Angew. Chem., Int. Ed. 37, 3366-3369.
6. Masciocchi, N., Bruni, S., Cariati, E., Cariati, F., Galli, S., and Sironi, A. (2001). " Extended polymorphism in copper(II) imidazolate polymers: a spectroscopic and XRPD structural study.," Inorg. Chem. 40, 5897-5905.
7. Masciocchi, N., Galli, S., and Sironi, A. (2005). " X-ray powder diffraction characterization of polymeric metal diazolates.," Comments Inorg. Chem. 26, 1-37.
8. Masciocchi, N., Galli, S., Sironi, A., Barea, E., Navarro, J. A. R., Salas, J. M., and Tabares, L. C. (2003). " Rich structural and magnetic chemistry of cobalt(II) pyrimidin-2-olate and pyrimidin-2-olate complexes. Synthesis, X-ray powder diffraction studies, and thermal behaviour.," Chem. Mater. 15, 2153-2160.
9. Maspero, A., Galli, S., Masciocchi, N., and Palmisano, G. (2008). " Facile preparation of polytopic azoles: synthesis, characterization, and X-ray powder diffraction studies of 1,4-bis(pyrazol-4-yl)- and 1,4-bis(tetrazol-5-yl) benzene.," Chem. Lett. 37, 956-957.
10. Navarro, J. A. R., Barea, E., Galindo, M. A., Salas, J. M., Romero, M. A., Quirós, M., Masciocchi, N., Galli, S., Sironi, A., and Lippert, B. (2005). " Soft functional polynuclear coordination compounds containing pyrimidine bridges.," J. Solid State Chem. 178, 2436-2451.
11. Navarro, J. A. R., Barea, E., Salas, J. M., Masciocchi, N., Galli, S., Sironi, A., Ania, C. O., and Parra, J. B. (2006). " H2, N2, CO, and C O2 sorption properties of a series of robust sodalite-type microporous coordination polymers.," Inorg. Chem. 45, 2397-2399.
12. Navarro, J. A. R., Barea, E., Salas, J. M., Masciocchi, N., Galli, S., Sironi, A., Ania, C. O., and Parra, J. B. (2007). " Borderline microporous-ultramicroporous palladium(II) coordination polymer networks. Effect of pore functionalisation on gas adsorption properties.," J. Mater. Chem. 17, 1939-1946.
13. Navarro, J. A. R., Barea, E., Rodriguez-Dieguez, A., Salas, J. M., Ania, C. O., Parra, J. B., Masciocchi, N., Galli, S., and Sironi, A. (2008). " Guest-induced modification of a magnetically active ultramicroporous, gismondine-like, copper(II) coordination network.," J. Am. Chem. Soc. 130, 3978-3984.
14. Shiu, K.-B., Yen, C.-H., Liao, F.-L., and Wang, S.-L. (2003). " trans-Diaquatetrakis(imidazole)nickel(II) dichloride.," Acta Crystallogr., Sect. E: Struct. Rep. Online 59, m1189-m1191.
15. Xamena, F. X. L. I., Abad, A., Corma, A., and Garcia, H. (2007). " MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF.," J. Catal. 250, 294-298.