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Volumn , Issue 35, 2008, Pages 5460-5463

Novel coordination modes for E4S3 cage molecules (E = P, As) in unprecedented quaternary As4S3(CuCl) n (n = 1,2) solid-state phases

Author keywords

Arsenic; Coordination modes; Copper; Halides; Solid state structures; Sulfur

Indexed keywords

ARSENIC COMPOUNDS; ATOMS; CHLORINE COMPOUNDS; CHROMIUM COMPOUNDS; COORDINATION REACTIONS; COPPER COMPOUNDS; CRYSTAL ATOMIC STRUCTURE; MOLECULES;

EID: 57149118634     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200801015     Document Type: Article
Times cited : (13)

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    • Crystal structure analyses: Data were collected with an Oxford Diffraction Gemini Ultra diffractometer (Cu-Kα- radiation) at 123 K. The structures were solved by direct methods and refined by full-matrix least-squares (SHELXL97 program) with all reflections. Data for 1: Yellow needles, 0.08 x 0.03 x 0.01 mm, orthorhombic, Pbcm, a, 10.861(1) Å, b, 11.002(1) Å, c, 7.192(1) Å. V, 859.41(3) Å3, Z, 4, ρcalcd, 3.825 g cm-3, θ, 4.07-62.04°, μ, 29.685 mm-1, 4591 measured reflections, 737 independent reflections (Rint, 0.0677, 661 observed reflections [I>2σI, 48 refined parameters, R1, 0.0463, wR2, 0.109, residual electron density 1.577/-1.327 eÅ-3. Data for 2: Yellow plates, 0.18 x 0.11 x 0.02 mm, monoclinic, P21
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.