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Owing to the poor solubility of the polymers 4 and 5, the molecular mass of the species in solution could not be determined.
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Owing to the poor solubility of the polymers 4 and 5, the molecular mass of the species in solution could not be determined.
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31
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34547753499
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The crystal structure analyses of 4 and 5·0. 25nC7H8 were performed on a STOE IPDS diffractometer with MoKα radiation (λ, 0.71073 Å, The structures were solved by direct methods with the program SIR-97[24, and full-matrix least-squares refinement on F 2 in SHELXL-97[25] was performed with anisotropic displacements for non-H atoms in 4. In the case of 5·0. 25nC7H8, only the heavier atoms (P, S, Mo, Ag) were refined anisotropically owing to poor crystal quality. Despite repeated attempts, higher-quality crystals of polymer 5 could not be grown. The hydrogen atoms in both structures were located in idealized positions and refined isotropically according to the riding model. The [Al(OC(CF 3)3)4, ion generally has a strong tendency to be rotationally disordered in two d
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8) and CCDC-634459 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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See the Supporting Information
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34547755035
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31P MAS NMR spectrum of polymer 4 at 190 K yields nevertheless a spectrum comparable to that of the polymer at room temperature.
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31P MAS NMR spectrum of polymer 4 at 190 K yields nevertheless a spectrum comparable to that of the polymer at room temperature.
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46
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34547737442
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Owing to the poor solubility of polymer 5, low-temperature NMR measurements could not be undertaken.
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Owing to the poor solubility of polymer 5, low-temperature NMR measurements could not be undertaken.
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