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Volumn 46, Issue 31, 2007, Pages 5966-5970

An unusual building block for supramolecular aggregates: The mixed group 15/16 element ligand complex [(Cp*Mo)2(μ,η3- P3)(μ,η2-PS)]

Author keywords

Group 11 metals; Molybdenum; Phosphorus; Sulfur; Supramolecular chemistry

Indexed keywords

COMPLEXATION; DERIVATIVES; LIGANDS; MOLYBDENUM; PHOSPHORUS; SULFUR;

EID: 34547806188     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701343     Document Type: Article
Times cited : (19)

References (49)
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    • Owing to the poor solubility of the polymers 4 and 5, the molecular mass of the species in solution could not be determined.
    • Owing to the poor solubility of the polymers 4 and 5, the molecular mass of the species in solution could not be determined.
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    • The crystal structure analyses of 4 and 5·0. 25nC7H8 were performed on a STOE IPDS diffractometer with MoKα radiation (λ, 0.71073 Å, The structures were solved by direct methods with the program SIR-97[24, and full-matrix least-squares refinement on F 2 in SHELXL-97[25] was performed with anisotropic displacements for non-H atoms in 4. In the case of 5·0. 25nC7H8, only the heavier atoms (P, S, Mo, Ag) were refined anisotropically owing to poor crystal quality. Despite repeated attempts, higher-quality crystals of polymer 5 could not be grown. The hydrogen atoms in both structures were located in idealized positions and refined isotropically according to the riding model. The [Al(OC(CF 3)3)4, ion generally has a strong tendency to be rotationally disordered in two d
    • 8) and CCDC-634459 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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    • 31P MAS NMR spectrum of polymer 4 at 190 K yields nevertheless a spectrum comparable to that of the polymer at room temperature.
    • 31P MAS NMR spectrum of polymer 4 at 190 K yields nevertheless a spectrum comparable to that of the polymer at room temperature.
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    • Owing to the poor solubility of polymer 5, low-temperature NMR measurements could not be undertaken.
    • Owing to the poor solubility of polymer 5, low-temperature NMR measurements could not be undertaken.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.