Characterization of reactive intermediates generated during photolysis of 4-acetoxy-4-aryl-2,5-cyclohexadienones: Oxenium ions and aryloxy radicals

Journal of the American Chemical Society

Volumn 130, Issue 47, 2008, Pages 16021-16030

  Wang, Yue Ting ^a   Jin, Kyoung Joo ^a   Leopold, Samuel H ^a   Wang, Jin ^b   Peng, Huo Lei ^b   Platz, Matthew S ^b   Xue, Jiadan ^c   Phillips, David Lee ^c   Glover, Stephen A ^d   Novak, Michael ^a  

^a MIAMI UNIVERSITY   (United States)

^b OHIO STATE UNIVERSITY   (United States)

^c UNIVERSITY OF HONG KONG   (Hong Kong)

^d UNIVERSITY OF NEW ENGLAND   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

DECAY (ORGANIC); ELECTROLYSIS; ESTERS; HYDROLYSIS; IONS; ORGANIC COMPOUNDS; PHENOLS; PLASMA DIAGNOSTICS; REACTION KINETICS; SOLUTIONS;

AQUEOUS SOLUTIONS; ARYLOXENIUM IONS; ARYLOXY; AZIDE IONS; BIPHASIC; DECAY KINETICS; DECAY PROCESSES; DECOMPOSITION KINETICS; DIRECT OBSERVATIONS; FIRST ORDERS; HYDROLYSIS REACTIONS; KINETIC MODELS; KINETIC SCHEMES; LASER FLASHES; LIFE-TIMES; MECHANISTIC STUDIES; OXIDATION REACTIONS; PHOTOLYSIS REACTIONS; REACTION PRODUCTS; REACTIVE INTERMEDIATES; REACTIVITY PATTERNS; RESONANCE RAMAN; REVERSIBLE FORMATIONS; ROOM TEMPERATURES; TIME-RESOLVED; UV-VIS SPECTRUMS;

PHOTOLYSIS;

4 ACETOXY 4 ARYL 2,5 CYCLOHEXADIENONE; ACETONITRILE; AZIDE; ION; OXENIUM; OXYGEN DERIVATIVE; PHENOL; PHENOL DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; CHEMICAL REACTION; DECOMPOSITION; HYDROLYSIS; ION TRAP MASS SPECTROMETRY; OXIDATION; PHOTOLYSIS; RAMAN SPECTROMETRY;

EID: 56749175085     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805336d     Document Type: Article

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