메뉴 건너뛰기




Volumn 47, Issue 49, 2008, Pages 9380-9382

Platinum-containing polyoxometalates

Author keywords

Oxo compounds; Platinum; Polyoxometalates; Structure elucidation; Vanadium

Indexed keywords

OXYGEN; PLATINUM; PORT TERMINALS; TRANSITION METALS; VANADIUM COMPOUNDS;

EID: 56749146146     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200800919     Document Type: Article
Times cited : (27)

References (18)
  • 7
    • 56749100219 scopus 로고    scopus 로고
    • Private communication; George Sheldrick, Dept. Structural Chemistry, University of Göttingen, Göttingen, Germany
    • Private communication; George Sheldrick, Dept. Structural Chemistry, University of Göttingen, 37077 Göttingen, Germany.
  • 16
    • 56749142571 scopus 로고    scopus 로고
    • There are two reasons for this: 1) The weighted average for their L-shell electrons differs by 1.0 keV for alpha and 1.3 keV for beta excitations. Given that the average width of the peaks at baseline is almost always over 1 keV for both solid and liquid samples, it is unlikely the two signals could be properly resolved for quantitative purposes; and 2 Lee et al. used a calibration curve spanning a 50000 ppm range. This is well beyond the linear range for these elements (a typical value is 1000 ppm but can be as high 10000 ppm with very well behaved samples and using a helium purge).
    • There are two reasons for this: 1) The weighted average for their L-shell electrons differs by 1.0 keV for alpha and 1.3 keV for beta excitations. Given that the average width of the peaks at baseline is almost always over 1 keV for both solid and liquid samples, it is unlikely the two signals could be properly resolved for quantitative purposes; and 2) Lee et al. used a calibration curve spanning a 50000 ppm range. This is well beyond the linear range for these elements (a typical value is 1000 ppm but can be as high 10000 ppm with very well behaved samples and using a helium purge).
  • 17
    • 0001770031 scopus 로고
    • Ed, A. P. Ginsberg, Wiley, New York
    • A. Tézé, G. Hervé in Inorganic Syntheses, Vol. 27 (Ed.: A. P. Ginsberg), Wiley, New York, 1990, p. 85.
    • (1990) Inorganic Syntheses , vol.27 , pp. 85
    • Tézé, A.1    Hervé, G.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.