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Crystal data for 2: C9H30B11NO, Mr, 287.3, monoclinic, space group P2 1/c, a, 7.924(3, b, 23.339(9, c, 9.662(4) Å, β, 97.49(1)°, V, 1772(1) Å3, T, 293 K, Z, 4, ρcalcd, 1.077 g cm-3, 2θmax, 50°, μ(MoKα, 0.71073 Å, absorption corrections applied by using SADABS,[18] relative transmission factors in the range 0.411-1.000. A total of 9415 reflections were collected and led to 3118 unique reflections, 3118 of which with I>2σ(I) were considered as observed, R1, 0.079, wR2F2, 0.199. Crystal data for 3: C24H34B11Cl2P, Mr=543.3, orthorhombic, space group P2 12121
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[20] All non-hydrogen atoms were refined anisotropically. All hydrogen atoms were geometrically fixed using the riding model. CCDC 699713, 699714, 699715 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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