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Volumn 47, Issue 49, 2008, Pages 9447-9449

Reaction of 13-vertex carboranes with nucleophiles: Unprecedented cage-carbon extrusion and formation of monocarba-closo-dodecaborate anions

Author keywords

Boron; Cage compounds; Carboranes; Cluster compounds; Nucleophilic addition

Indexed keywords

BORON; BORON COMPOUNDS; CARBON; CHEMICAL REACTIONS; EXTRUSION; FORMING; HYDROGEN; HYDROGEN BONDS; NEGATIVE IONS; NUCLEOPHILES;

EID: 56749142944     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200804249     Document Type: Article
Times cited : (28)

References (32)
  • 1
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    • For reviews, see: a) L. Deng, Z. Xie, Organometallics 2007, 26, 1832;
    • (2007) Organometallics , vol.26 , pp. 1832
    • Deng, L.1    Xie, Z.2
  • 18
    • 56749167608 scopus 로고    scopus 로고
    • Crystal data for 2: C9H30B11NO, Mr, 287.3, monoclinic, space group P2 1/c, a, 7.924(3, b, 23.339(9, c, 9.662(4) Å, β, 97.49(1)°, V, 1772(1) Å3, T, 293 K, Z, 4, ρcalcd, 1.077 g cm-3, 2θmax, 50°, μ(MoKα, 0.71073 Å, absorption corrections applied by using SADABS,[18] relative transmission factors in the range 0.411-1.000. A total of 9415 reflections were collected and led to 3118 unique reflections, 3118 of which with I>2σ(I) were considered as observed, R1, 0.079, wR2F2, 0.199. Crystal data for 3: C24H34B11Cl2P, Mr=543.3, orthorhombic, space group P2 12121
    • [20] All non-hydrogen atoms were refined anisotropically. All hydrogen atoms were geometrically fixed using the riding model. CCDC 699713, 699714, 699715 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 24
    • 3042779638 scopus 로고    scopus 로고
    • It has been reported that PPh3 attacks the nonclassical carbon atom of the μ-(9,10-HR'C) unit in [7-R-μ-(9,10-HR'C)-7-nido- CB10H11, J. Bould, A. Laromaine, C. Viñas, F. Teixidor, L. Barton, N. P. Rath, R. E. K. Winter, R. Kivek-äs, R. Sillanpää, Organometallics 2004, 23, 3335
    • -: J. Bould, A. Laromaine, C. Viñas, F. Teixidor, L. Barton, N. P. Rath, R. E. K. Winter, R. Kivek-äs, R. Sillanpää, Organometallics 2004, 23, 3335.
  • 26
    • 84906432916 scopus 로고    scopus 로고
    • For reviews, see: a, Eds, D. M. P. Mingos, R. H. Crabtree, Elsevier, Oxford
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    • (2007) Comprehensive Organometallic Chemistry III , vol.3 , pp. 175
    • Hosmane, N.S.1    Maguire, J.A.2
  • 29
    • 0000622484 scopus 로고
    • Eds, E. W. Abel, F. G. A. Stone, G. Wilkinson, Pergamon, Oxford
    • d) R. N. Grimes in Comprehensive Organometallic Chemistry II, Vol. 1 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 373.
    • (1995) Comprehensive Organometallic Chemistry II , vol.1 , pp. 373
    • Grimes, R.N.1
  • 31
    • 0004150157 scopus 로고    scopus 로고
    • SHELXTL 5.10 for Windows NT: Structure Determination Software Programs, Bruker Analytical X-ray Systems, Inc., Madison, Wisconsin, USA
    • G. M. Sheldrick, SHELXTL 5.10 for Windows NT: Structure Determination Software Programs, Bruker Analytical X-ray Systems, Inc., Madison, Wisconsin, USA, 1997.
    • (1997)
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.