Carbon extrusion in 1,2-dicarba-closo-dodecaboranes: Regioselective boron substitution in ten-vertex closo-monocarbaborane anions

Angewandte Chemie - International Edition

Volumn 44, Issue 15, 2005, Pages 2220-2222

  Laromaine, Anna ^a   Teixidor, Francesc ^a   Viñas, Clara ^a  

^a INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA ICMAB CSIC   (Spain)

Author keywords

Boron; Carboranes; Rearrangement; Regioselectivity; Synthetic methods

Indexed keywords

BORON; CARBON; EXTRUSION; NEGATIVE IONS; SUBSTITUTION REACTIONS;

CARBON ATOM; CARBON EXTRUSION; DEBORONATION; DICARBABORANE;

ORGANIC COMPOUNDS;

EID: 17644399514     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462209     Document Type: Article

References (32)

1. B. Stíbr, Chem. Rev. 1992, 92, 225.
2. V. I. Bregadze, Chem. Rev. 1992, 92, 209.
3. a) Z. Xie, T. Jelinek, R. Bau, C. Reed, J. Am. Chem. Soc. 1994, 116, 1907;
4. b) C. Reed, Acc. Chem. Res. 1998, 31, 133;
5. c) S. Strauss, Chem. Rev. 1993, 93, 927;
6. d) B. T. King, Z. Janousek, B. Grüner, M. Trammell, B. C. Noll, J. Michl, J. Am. Chem. Soc. 1996, 118, 3313.
7. P. Kaszynski, Collect. Czech. Chem. Commun. 1999, 64, 895, and references therein.
8. a) K. Nestor, B. Stíbr, J. D. Kennedy, M. Thornton-Pett, T. Jelinek, Collect. Czech. Chem. Commun. 1992, 57, 1262;
9. b) T. Jelinek, B. Stíbr, J. Plesek, M. Thornton-Pett, J. D. Kennedy, J. Chem. Soc. Dalton Trans. 1997, 4231.
10. B. Brellochs in Contemporary Boron Chemistry (Eds.: M. G. Davidson, A. K. Hughes, T. B. Marder, K. Wade), Royal Society of Chemistry, Cambridge, 2000, pp. 212.
11. a) J. Plesek, T. Jelinek, B. Stíbr, S. Hemánek, J. Chem. Soc. Chem. Commun. 1988, 348;
12. b) T. Jelinek, B. Stíbr, J. Plesek, J. D. Kennedy, M. Thornton-Pett, J. Chem. Soc. Dalton Trans. 1995, 431.
13. a) A. Nicolaides, L. Radom, J. Am. Chem. Soc. 1994, 116, 9769;
14. b) S. K. Shin, Chem. Phys. Lett. 1997, 280, 260;
15. c) C. Lifshitz, Acc. Chem. Res. 1994, 27, 138;
16. d) C.-H. Shin, K-C. Park, S.-J. Kim, B. Kim, Bull. Korean Chem. Soc. 2002, 23, 337.
17. E. D. Jemmis, E. G. Jayasree, Inorg. Chem. 2003, 42, 7725.
18. M. L. McKee, M. Bühl, P. von R. Schleyer, Inorg. Chem. 1993, 32, 1712.
19. a) G. B. Dunks, R. J. Wiersema, M. F. Hawthorne, J. Chem. Soc. Chem. Commun. 1972, 899;
20. b) G. B. Dunks, R. J. Wiersema, M. F. Hawthorne, J. Am. Chem. Soc. 1973, 95, 3174;
21. c) J. Plesek, T. Jelinek, B. Stíbr, S. Hermánek, J. Chem. Soc. Chem. Commun. 1988, 348.
22. a) D. Grafstein, J. Dvorak, Inorg. Chem. 1963, 2, 1128;
23. b) L. Zakharkin, V. Kalinin, L. Podvisotskaya, Izv. Akad. Nauk SSSR Ser. Khim. 1967, 10, 2310;
24. c) Y. Stanko, V. Goltypin, V. Brattsev, Zh. Obshch. Khim. 1969, 39, 1175.
25. J. Plesek, B. Stíbr, X. L. R. Fontaine, T. Jelinek, M. Thornton-Pett, S. Hermánek, J. D. Kennedy, Inorg. Chem. 1994, 33, 2994.
26. C. Viñas, G. Barberà, F. Teixidor, J. Organomet. Chem. 2002, 642, 16.
27. J. Bould, A. Laromaine, C. Viñas, F. Teixidor, L. Barton, N. P. Rath, R. E. K. Winter, R. Kivekäs, R. Sillanpää, Organometallics 2004, 23, 3335.
28. a) M. Lamrani, S. Gómez, C. Viñas, F. Teixidor, R. Sillanpää, R. Kivekäs, New J. Chem. 1996, 20, 909;
29. b) F. Teixidor, S. Gómez, M. Lamrani, C. Viñas, R. Sillanpää, R. Kivekäs, Organometallics 1997, 16, 1278.
30. a) S. V. Ivanov, J. J. Rockwell, S. M. Miller, O. P. Anderson, K. A. Solntsev, S. H. Strauss, Inorg. Chem. 1996, 35, 7882;
31. b) N. J. Bullen, A. Franken, C. A. Kilner, J. D. Kennedy, Chem. Commun. 2003, 1684.
32. F. Teixidor, C. Viñas, R. W. Rudolph, Inorg. Chem. 1986, 25, 3339.