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4] in DCE, in which cation dimerization should be less favorable. The results were very similar to those reported here for MeCN.
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4] in DCE, in which cation dimerization should be less favorable. The results were very similar to those reported here for MeCN.
-
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64
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56649105675
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Despite many attempts, with different solvents and reducing agents, we have not been able to isolate 2a or 2b. Similar difficulties with other monofunctional 1,2,3-dithiazolyls, and their selenium analogues, have been encountered before, although the naphthalene version of 2a has been structurally characterized see ref 14
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4] affords a black microcrystalline deposit on the electrode. This material is, we presume, the same as that generated by chemical reduction.
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4] affords a black microcrystalline deposit on the electrode. This material is, we presume, the same as that generated by chemical reduction.
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69
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56649113382
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+ is remarkably robust (air stable). Its infrared spectrum is strong, reproducible and not that of elemental tellurium; it also provided a good powder X-ray diffraction pattern. While we were unable to index this pattern, it was certainly not that of elemental tellurium.
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+ is remarkably robust (air stable). Its infrared spectrum is strong, reproducible and not that of elemental tellurium; it also provided a good powder X-ray diffraction pattern. While we were unable to index this pattern, it was certainly not that of elemental tellurium.
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