Pressure-induced magnetic switching and linkage isomerism in K 0.4Fe4[Cr(CN)6]2.8·16H 2O: X-ray absorption and magnetic circular dichroism studies

Journal of the American Chemical Society

Volumn 130, Issue 46, 2008, Pages 15519-15532

  Coronado, Eugenio ^a   Giménez López, M Carmen ^a   Korzeniak, Tomasz ^a,f   Levchenko, Georgiy ^a   Romero, Francisco M ^a   Segura, Alfredo ^a   García Baonza, Valentín ^b   Cezar, Julio C ^c   De Groot, Frank M F ^d   Milner, Alla ^e   Paz Pasternak, Moshe ^e  

^a UNIVERSITY OF VALENCIA   (Spain)

^b UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^c EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^d UTRECHT UNIVERSITY   (Netherlands)

^e TEL AVIV UNIVERSITY   (Israel)

^f JAGIELLONIAN UNIVERSITY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CHAINS; CHROMIUM; CIRCULAR DICHROISM SPECTROSCOPY; DICHROISM; ELECTROMAGNETIC WAVE ABSORPTION; ELECTRON TRANSITIONS; ENERGY ABSORPTION; IRON COMPOUNDS; ISOMERIZATION; ISOMERS; MAGNETIC MATERIALS; MAGNETIC PROPERTIES; MAGNETIC SUSCEPTIBILITY; MAGNETISM; MAGNETS; MOLYBDENUM; OPTICAL PROPERTIES; SPECTRUM ANALYSIS; SPIN DYNAMICS; STEREOCHEMISTRY; VANADIUM COMPOUNDS; X RAY ABSORPTION; X RAY SPECTROSCOPY;

AC MAGNETIC SUSCEPTIBILITIES; AMBIENT CONDITIONS; APPLIED PRESSURES; CRITICAL TEMPERATURES; CUBIC LATTICES; LIGAND FIELDS; LINKAGE ISOMERIZATION; MAGNETIC CIRCULAR DICHROISMS; MAGNETIC SWITCHING; PRESSURE CONDITIONS; PRUSSIAN BLUE ANALOGUES; SPIN STATES; SSBAUER SPECTROSCOPIES;

ABSORPTION SPECTROSCOPY;

FERROUS ION;

ARTICLE; CIRCULAR DICHROISM; CRYSTAL STRUCTURE; ISOMERISM; ISOMERIZATION; MAGNETISM; MOSSBAUER SPECTROSCOPY; PRESSURE MEASUREMENT; RAMAN SPECTROMETRY; ROENTGEN SPECTROSCOPY; TEMPERATURE; X RAY ABSORPTION SPECTROSCOPY; X RAY ANALYSIS; X RAY DIFFRACTION;

CHROMIUM COMPOUNDS; CRYSTALLIZATION; CYANIDES; IRON COMPOUNDS; ISOMERISM; MAGNETICS; PRESSURE; SPECTRUM ANALYSIS; TEMPERATURE; WATER; X-RAY DIFFRACTION; X-RAYS;

EID: 56449089594     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8047046     Document Type: Article

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76. 2O: C, 17.56; H, 3.19; N, 20.48. Found: C, 17.53; H, 3.21; N, 20.14. Metal Anal.: Cr, 39.1; Fe, 56.5; K, 4.4. Found: Cr, 37.9; Fe, 57.5; K, 4.6. The powder XRD data for this sample were very similar to those for 1 (see the Supporting Information).