Competitive 15M kinetic isotope effects of nitrogenase-catalyzed dinitrogen reduction

Journal of the American Chemical Society

Volumn 126, Issue 40, 2004, Pages 12768-12769

  Sra, Amandeep K ^a,d   Hu, Yilin ^b   Martin, Glen E ^c   Snow, Daniel D ^c   Ribbe, Markus W ^b   Kohen, Amnon ^a  

^a E11 SSH   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^d TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ISOTOPE; NITROGEN; NITROGEN 15; NITROGENASE;

ARTICLE; AZOTOBACTER VINELANDII; CALCULATION; CATALYSIS; CATALYST; CHEMICAL BOND; CRYSTAL STRUCTURE; ENRICHMENT CULTURE; ENZYME ACTIVITY; KINETIC ISOTOPE EFFECT; KINETICS; NITROGEN FIXATION; NONHUMAN; REACTION ANALYSIS; REDUCTION; CHEMISTRY; ENZYMOLOGY; METABOLISM; OXIDATION REDUCTION REACTION;

AZOTOBACTER VINELANDII; CATALYSIS; KINETICS; NITROGEN; NITROGEN FIXATION; NITROGEN ISOTOPES; NITROGENASE; OXIDATION-REDUCTION;

EID: 5644240807     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0458470     Document Type: Article

References (17)

1. Northrop, D. B. In Enzyme mechanism from isotope effects; Cook, P. F., Ed.; CRC Press: Boca Raton, FL, 1991; pp 181-202.
2. Cleland, W. W. In Enzyme Mechanism from Isotope Effects; Cook, P. F., Ed.; CRC Press: Boca Raton, FL, 1991; pp 247-268.
3. Thorneley, R. N. F.; Lowe, D. F. In Molybdenum Enzymes; Sprio, T. G., Ed.; John Wiley and Sons Inc.: New York, 1985; Vol. 7, pp 221-284, and many references cited therein.
4. Wilson, P. E.; Nyborg, A. C.; Watt, G. D. Biophys. Chem. 2001, 91, 281-304.
5. Kim, J.; Rees, D. C. Nature 1992, 553-560.
6. Rees, D. C.; Howard, J. B. Curr. Opin. Chem. Biol. 2000, 559-566.
7. Einsle, O.; Tezcan, A.; Andrade, S. L. A.; Schmid, B.; Yoshida, M.; Howard, J. B.; Rees, D. C. Science 2002, 297, 1696-1700.
8. See Supporting Information for more details.
9. Cook, P. F. Enzyme mechanism from isotope effects; CRC Press: Boca Raton, FL, 1991.
10. Kohen, A.; Limbach, H. H. Isotope effects in chemistry and biology; Marcel-Dekker and CRC Press: New York, 2004.
11. Burris, R. H.; Miller, C. E. Science 1941, 93, 114-115.
12. Burgess, B. K.; Lowe, D. J. Chem. Rev. 1996, 96, 2983-3011.
13. Weiss, P. M. In Enzyme Mechanism from Isotope Effects; Cook, P. F., Ed.; CRC Press: Boca Raton, FL, 1991; pp 291-311.
14. Tian, G.; Berry, J. A.; Klinman, J. P. Biochemistry 1994, 33, 226-234.
15. Glickman, M. H.; Cliff, S.; Thiemens, M.; Klinman, J. P. J. Am. Chem. Soc. 1997, 119, 11357-11361.
16. Edens, W. A.; Urbauer, J. L.; Cleland, W. W. Biochemistry 1997, 36, 1141-1147.
17. Hermes, J. D.; Roeske, C. A.; Oleary, M. H.; Cleland, W. W. Biochemistry 1982, 21, 5106-5114.