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Volumn 14, Issue 33, 2008, Pages 10184-10191

Recent synthetic applications of manganese in organic synthesis

Author keywords

Amides; Manganese; Metalation; Organomanganese compounds; Transmetalation

Indexed keywords

AMIDES; MANGANESE; MANGANESE COMPOUNDS; ORGANIC COMPOUNDS; ORGANOMETALLICS;

EID: 56349147351     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800796     Document Type: Article
Times cited : (27)

References (47)
  • 2
    • 56349136686 scopus 로고    scopus 로고
    • Organomanganous Reagents: J. F. Normant, G. Cahiez, in Modern Synthetic Methods, 3 (Ed.: R. Scheffold), Springer, Berlin, 1983, 173-216.
    • "Organomanganous Reagents": J. F. Normant, G. Cahiez, in Modern Synthetic Methods, Vol. 3 (Ed.: R. Scheffold), Springer, Berlin, 1983, 173-216.
  • 3
    • 0000604229 scopus 로고
    • O. Cahiez. An. Quim. 1995, 91, 561-578.
    • (1995) An. Quim , vol.91 , pp. 561-578
    • Cahiez, O.1
  • 5
    • 56349122345 scopus 로고    scopus 로고
    • To see a review regarding the synthesis and synthetic applications of various active metals: A. Guijarro, C. Gómez, M. Yus, Trends Org. Chem. 2000, 3, 65-91.
    • To see a review regarding the synthesis and synthetic applications of various active metals: A. Guijarro, C. Gómez, M. Yus, Trends Org. Chem. 2000, 3, 65-91.
  • 6
    • 56349139415 scopus 로고    scopus 로고
    • The reactions promoted by manganese present different types of selectivities. Thus, most of the transformations were compatible with the presence of several functional groups.[21,22,27-30,32-38,40-42] Other reactions can be carried out with starting materials highly prone of suffering enolization.[22,40-42] The reported β-elimination reactions take place with complete or high diastereoselectivity.[22,40-42
    • The reactions promoted by manganese present different types of selectivities. Thus, most of the transformations were compatible with the presence of several functional groups.[21,22,27-30,32-38,40-42] Other reactions can be carried out with starting materials highly prone of suffering enolization.[22,40-42] The reported β-elimination reactions take place with complete or high diastereoselectivity.[22,40-42]
  • 7
    • 56349105858 scopus 로고    scopus 로고
    • Aldrich catalogue (2007-2008, powder manganese 325 mesh, 250 g, 37 €
    • Aldrich catalogue (2007-2008): powder manganese (325 mesh): 250 g = 37 €.
  • 8
    • 56349134747 scopus 로고    scopus 로고
    • No special precaution is required due to the low toxicity of manganese and manganese salts obtained after the aqueous workup of organomanganese reactions; see reference [3
    • No special precaution is required due to the low toxicity of manganese and manganese salts obtained after the aqueous workup of organomanganese reactions; see reference [3].
  • 9
    • 56349121898 scopus 로고    scopus 로고
    • 0 -1.03 V; Handbook of Chemistry and Physics, 62nd ed., CRC, Boca Raton, FL, 1982.
    • 0 -1.03 V; Handbook of Chemistry and Physics, 62nd ed., CRC, Boca Raton, FL, 1982.
  • 43
    • 0032473838 scopus 로고    scopus 로고
    • 2-promoted sequential reactions, see: a G. A. Molander, C.R. Harris, Tetrahedron 1998, 54, 3321-3354;
    • 2-promoted sequential reactions, see: a) G. A. Molander, C.R. Harris, Tetrahedron 1998, 54, 3321-3354;


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.