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Volumn 86, Issue 7, 2001, Pages 1271-1274

Time-temperature superposition in viscous liquids

Author keywords

[No Author keywords available]

Indexed keywords

DIELECTRIC LOSSES; DIELECTRIC MATERIALS; DIELECTRIC RELAXATION; ELECTRIC VARIABLES MEASUREMENT; LIQUIDS; LOW TEMPERATURE EFFECTS;

EID: 14344281259     PISSN: 00319007     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevLett.86.1271     Document Type: Article
Times cited : (154)

References (50)
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    • Time-temperature superposition is such an enormous subject that it is impossible to get a full view of it. We here present the history of TTS as we recall it from many years of reading the literature on nonpolymeric viscous liquids.
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    • note
    • Curiously, our very best example of TTS derives from a five year old bottle of triphenyl phosphite (97%) (data shown in Fig. 1 of N. B. Olsen, T. Christensen, and J. C. Dyre, e-print cond-mat/0006165). For this liquid, which has an α loss twice as large as that of newly purchased (99%) triphenyl phosphite, deviations from TTS are consistent with those expected from the 1 mK temperature inaccuracy of our cryostate (since the writing of Ref. [26] the temperature stability has been improved from 5 to 1 mK). Since five year old measurements on the 97% bottle were virtually identical to our present 99% measurements, it appears that the "old" liquid has undergone some chemical decomposition. The minimum slope above the loss peak of the old liquid is -0.503; the corresponding number for the "new" liquid is -0.482.
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