Kinetics and mechanism of the anilinolysis of S-aryl N-arylthiocarbamates in acetonitrile

Journal of Physical Organic Chemistry

Volumn 21, Issue 11, 2008, Pages 1014-1019

  Sung, Dae Dong ^a   Jang, Hee Man ^a   Jung, Dae Il ^a   Leeb, Ikchoon ^b  

^a Dong A University   (South Korea)

^b Inha University   (South Korea)

Author keywords

Cross interaction constant; Kinetic isotope effect; S aryl N arylthiocarbamate; Stepwise mechanism; Zwitterionic intermediate

Indexed keywords

ACETONITRILE; AMINATION; AMINES; ANILINE; FLOW INTERACTIONS; NUCLEOPHILES; ORGANIC COMPOUNDS; REACTION RATES;

CROSS-INTERACTION CONSTANT; KINETIC ISOTOPE EFFECT; S-ARYL N-ARYLTHIOCARBAMATE; STEPWISE MECHANISM; ZWITTERIONIC INTERMEDIATE;

RATE CONSTANTS;

EID: 55849152060     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1418     Document Type: Article

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