Synthesis, characterisation of two hexa-iron clusters with {Fe2S2(CO)x} (x = 5 or 6) fragments and investigation into their inter-conversion

Journal of Organometallic Chemistry

Volumn 693, Issue 25, 2008, Pages 3751-3759

  Zhong, Wei ^a   Zampella, Giuseppe ^b   Li, Zhimei ^a   De Gioia, Luca ^b   Liu, Yinqiu ^c   Zeng, Xirui ^c   Luo, Qiuyan ^c   Liu, Xiaoming ^a  

^a NANCHANG UNIVERSITY   (China)

^b UNIVERSITY OF MILANO BICOCCA   (Italy)

^c JINGGANGSHAN UNIVERSITY   (China)

Author keywords

FeFe hydrogenase; DFT calculations; Hexa iron clusters; Iron sulfur carbonyl complexes; Reaction mechanism

Indexed keywords

ATOMIC PHYSICS; ATOMS; BINDING SITES; BIOCHEMISTRY; BUTANE; CHAINS; DENSITY FUNCTIONAL THEORY; EQUILIBRIUM CONSTANTS; IRON COMPOUNDS; LIGANDS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROBABILITY DENSITY FUNCTION; SULFUR; SULFUR COMPOUNDS; TOLUENE;

[FEFE]-HYDROGENASE; CHARACTERISATION; CO ATMOSPHERES; CO LIGANDS; CO UPTAKES; DFT CALCULATIONS; DITHIOL; ENDERGONIC PROCESSES; FE ATOMS; HEXA-IRON CLUSTERS; IRON CLUSTERS; LIGAND BINDINGS; NMR SPECTROSCOPIES; REACTION BARRIERS; REACTION MECHANISM; REVERSE PROCESSES; THIOLATE; VACANT SITES;

CARBON MONOXIDE;

EID: 55349104438     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.09.021     Document Type: Article

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