Synthesis and characterization of starlike complexes containing three terminal butterfly Fe/S cluster cores generated via reactions of the three-μ-CO-containing trianions {[(μ-CO)Fe2(CO) 6]3[(μ-SCH2CH2) 3]}3-

Organometallics

Volumn 24, Issue 15, 2005, Pages 3764-3771

  Song, Li Cheng ^a   Cheng, Jia ^a   Gong, Feng Hua ^a   Hu, Qing Mei ^a   Yan, Jing ^a  

^a NANKAI UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; CRYSTAL STRUCTURE; NEGATIVE IONS; REACTION KINETICS; SINGLE CRYSTALS; SPECTRUM ANALYSIS; X RAY DIFFRACTION;

CLUSTER CORES; ELECTROPHILES; ELEMENTAL ANALYSIS; TRIANIONS;

SYNTHESIS (CHEMICAL);

EID: 23044481570     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050333a     Document Type: Article

References (45)

1. (a) Ogino, H.; Inomata, S.; Tobita, H. Chem. Rev. 1998, 98, 2093.
2. (b) Song, L.-C. In Trends in Organometallic Chemistry; Atwood, J. L., Corriu, R., Cowley, A. H., Lappert, M. F., Nakamura, A., Pereyre, M., Eds.; Research Trends: Trivandrum, India, 1999; Vol. 3, p 1.
3. (c) Song, L.-C. Acc. Chem. Res. 2005, 38, 21.
4. (a) Coucouvanis, D. Acc. Chem. Res. 1991, 24, 1.
5. (b) Karlin, K. D. Science 1993, 261, 701.
6. (c) Rao, P. V.; Holm, R. H. Chem. Rev. 2004, 104, 527.
7. (a) Gloaguen, F.; Lawrence, J. D.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 9476.
8. (b) Gloaguen, F.; Lawrence, J. D.; Schmidt, M.; Wilson, S. R.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 12518.
9. (c) Lyon, E. J.; Georgakaki, I. P.; Reibenspies, J. H.; Darensbourg, M. Y. J. Am. Chem. Soc. 2001, 123, 3268.
10. (d) Darensbourg, M. Y.; Lyon, E. J.; Zhao, X.; Georgakaki, I. P. PNAS 2003, 100, 3683.
11. (e) Song, L.-C.; Yang, Z.-Y.; Bian, H.-Z.; Hu, Q.-M. Organometallics 2004, 23, 3082.
12. For single-butterfly, one-μ-CO-containing monoanion 1, see for example: (a) Seyferth, D.; Womack, G. B.; Dewan, J. C. Organometallics 1985, 4, 398.
13. (b) Seyferth, D.; Hoke, J. B.; Dewan, J. C. Organometallics 1987, 6, 895.
14. (c) Seyferth, D.; Ruschke, D. P.; Davis, W. M.; Cowie, M.; Hunter, A. D. Organometallics 1994, 13, 3834.
15. (d) Delgado, E.; Hernández, E.; Rossell, O.; Seco, M.; Puebla, E. G.; Ruiz, C. J. Organomet. Chem. 1993, 455, 177.
16. (e) Song, L.-C.; Hu, Q.-M. J. Organomet. Chem. 1991, 414, 219.
17. (f) Song, L.-C.; Yan, C.-G.; Hu, Q.-M.; Wang, R.-J.; Mak, T. C. W.; Huang, X.-Y. Organometallics 1996, 15, 1535.
18. (g) Song, L.-C.; Fan, H.-T.; Hu, Q.-M.; Qin, X.-D.; Zhu, W.-F.; Chen, Y.; Sun, J. Organometallics 1998, 17, 3454.
19. (h) Song, L.-C.; Lu, G.-L.; Hu, Q.-M.; Fan, H.-T.; Chen, Y.; Sun, J. Organometallics 1999, 18, 3258.
20. (i) Song, L.-C.; Lu, G.-L.; Hu, Q.-M.; Sun, J. Organometallics 1999, 28, 2700.
21. (j) Wang, Z.-X.; Jia, C.-S.; Zhou, Z.-Y. Zhou, X.-G. J. Organomet. Chem. 1999, 580, 201.
22. For double-butterfly, one-μ-CO-containing monoanion 2, see for example: (a) Song, L.-C.; Hu, Q.-M.; Fan, H.-T.; Sun, B.-W.; Tang, M.-Y.; Chen, Y.; Sun, Y. Sun, C.-X.; Wu, Q.-J. Organometallics 2000, 19, 3909.
23. (b) Song, L.-C.; Hu, Q.-M.; Sun, B.-W.; Tang, M.-Y.; Lu G.-L. Inorg. Chim. Acta 2003, 346, 12.
24. (c) Song, L.-C.; Hu, Q.-M.; Sun, B.-W.; Tang, M.-Y.; Yang, J.; Hua, Y.-J. Organometallics 2002, 21, 1627.
25. For double-butterfly, two-μ-CO-containing dianion 3, see for example: (a) Song, L.-C.; Fan, H.-T.; Hu, Q.-M. J. Am. Chem. Soc. 2002, 124, 4566.
26. (b) Song, L.-C.; Fan, H.-T.; Hu, Q.-M.; Yang, Z.-Y.; Sun, Y.; Gong F.-H. Chem. Eur. J. 2003, 9, 170.
27. (c) Song, L.-C.; Gong, F.-H.; Meng T.; Ge, J.-H.; Cui, L.-N.; Hu, Q.-M. Organometallics 2004, 23, 823.
28. Song, L.-C.; Cheng, J.; Hu, Q.-M.; Gong, F.-H.; Bian, H.-Z.; Wang, L.-X. Organometallics 2005, 24, 472.
29. Seyferth, D.; Hoke, J. B. Organometallics 1988, 7, 524.
30. Song, L.-C.; Lu, G.-L.; Hu, Q.-M.; Qin, X.-D.; Sun, C.-X.; Yang J.; Sun, J. J. Organomet. Chem. 1998, 571, 55.
31. Seyferth, D.; Womack, G. B.; Archer, C. M.; Fackler, J. P., Jr.; Marler, D. O. Organometallics 1989, 8, 443.
32. Song, L.-C.; Yan, C.-G.; Hu, Q.-M.; Wang R.-J.; Mak, T. C. W. Organometallics 1995, 14, 5513.
33. Song, L.-C.; Li, Y.; Hu, Q.-M.; Liu, R.-G.; Wang, J.-T. Acta Chim. Sin. 1990, 48, 1180.
34. Seyferth, D.; Henderson, R. S.; Song, L.-C. Organometallics 1982, 1, 125.
35. Song, L.-C.; Lu, G.-L.; Hu, Q.-M.; Sun, J. Organometallics 1999, 78, 5429.
36. Le Borgne, G.; Mathieu, R. J. Organomet. Chem. 1981, 208, 201.
37. Song, L.-C.; Hu, Q.-M.; Zhou, Z.-Y.; Hu, G.-Z. Chin. J. Org. Chem. 1991, 11, 533.
38. Song, L.-C.; Wang, R.-J.; Li, Y.; Wang, H.-G.; Wang, J.-T. Chin. J. Org. Chem. 1989, 9, 512.
39. Seyferth, D.; Womack, G. B.; Dewan, J. C. Organometallics 1985, 4, 398.
40. King, R. B. Organometallic Syntheses; Transition-Metal Compounds; Academic Press: New York, 1965; Vol. 1, p 95.
41. Horner, L.; Beck, P.; Toscano, V. G. Chem. Ber. 1961, 94, 2122.
42. Harley-Mason, J. J. Chem. Soc. 1947, 320.
43. Whitesides, G. M.; Houk, J. J. Am. Chem. Soc. 1987, 109, 6825.
44. Harpp, D. N.; Mathiaparanam, P. J. Org. Chem. 1972, 37, 1367.
45. Vaughan, W. R.; Carlson, R. D. J. Am. Chem. Soc. 1962, 84, 769.