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Volumn 47, Issue 20, 2008, Pages 9125-9127

Reactions of ruthenium complexes having pyridyl-containing ligands, 2-pyridinecarboxylato and 2,2′-bipyridine, with an azide ion: Formation of nitrido-bridged diruthenium complexes

Author keywords

[No Author keywords available]

Indexed keywords

2,2' BIPYRIDINE; AZIDE; CARBOXYLIC ACID; LIGAND; ORGANOMETALLIC COMPOUND; RUTHENIUM;

EID: 55249083083     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801070a     Document Type: Article
Times cited : (14)

References (37)
  • 6
    • 4243475756 scopus 로고    scopus 로고
    • Nitric Oxide Chemistry
    • Richter-Addo, G. B, Legdzins, P, Burstyn, J, Eds, American Chemical Society: Washington, DC
    • (c) Richter-Addo, G. B., Legdzins, P., Burstyn, J., Eds. Nitric Oxide Chemistry. In Chemical Review; American Chemical Society: Washington, DC, 2002; p 102.
    • (2002) Chemical Review , pp. 102
  • 26
    • 55249123953 scopus 로고    scopus 로고
    • Yield: 87, Anal. Found: C, 32.74; H, 2.04; N, 9.43. Calcd for [RuCl(NO)(pyca)(bpy)]PF6: C, 32.58; H, 2.05; N, 9.50. FAB-MS (m/z, 445 (M, PF6, IR (KBr, ν(NO) 1901 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 7.65 (dd, J, 5.8 and 5.8 Hz, 1H, 7.95 (dd, J, 5.8 and 5.8 Hz, 1H, 8.00 (d, J, 5.8 Hz, 1H, 8.07 (dd, J, 5.5 and 5.5 Hz, 1H, 8.20 (d, J, 7.8 Hz, 1H, 8.37-8.42 (m, 2H, 8.50 (dd, J, 8.2 and 7.6 Hz, 1H, 8.60 (dd, J, 8.2 and 8.2 Hz, 2H, 8.86 (d, J, 5.5 Hz, 1H, 9.47 (d, J, 5.5 Hz, 1H, 13C NMR CD3CN, δ 126.01, 126.10, 129.37, 129.44, 129.57, 132.36, 143.86, 144.31, 144.51, 149.97, 152.09, 152.40, 153.01, 155.98, 156.83, 178.51
    • 3CN): δ 126.01, 126.10, 129.37, 129.44, 129.57, 132.36, 143.86, 144.31, 144.51, 149.97, 152.09, 152.40, 153.01, 155.98, 156.83, 178.51.
  • 28
    • 55249117385 scopus 로고    scopus 로고
    • Yield: 51, Anal. Found: C, 39.43; H, 3.61; N, 9.15. Calcd for, Ru(OC2H5)(pyca)(bpy)}2(μ-N)]PF 6·5H2O: C, 39.38; H, 4.04; N, 8.93. FAB-MS (m/z, 864 (M, PF6, 774 (M, PF6, 2OC 2H5, IR: ν(Ru-N-Ru) 1018 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 1.34 (dd, J, 6.9 and 6.9 Hz, 6H, 3.47 (dq, J, 9.2 and 6.9 Hz, 2H, 3.57 (dq, J, 9.2 and 6.9 Hz, 2H, 6.92 (dd, J, 5.5 and 5.5 Hz, 2H, 7.02 (d, J, 5.5 Hz, 2H, 7.81 (dd, J, 7.8 and 5.5 Hz, 2H, 7.94 (d, J, 7.8 Hz, 2H, 7.99-8.04 (m, 6H, 8.09 (d, J, 7.8 Hz, 2H, 8.15 (dd, J, 7.8 and 7.8 Hz, 2H, 8.27 (dd, J, 7.8 and 7.8 Hz, 2H, 9.64 (d, J, 5.5 Hz, 2H, 10.11 (d, J, 5.5 Hz, 2H, 13C NMR CD3CN, Me4Si, δ 21.03, 66.75, 125.17, 125.22, 128.39, 128
    • 4Si): δ 21.03, 66.75, 125.17, 125.22, 128.39, 128.68, 129.35, 130.32, 142.10, 142.18, 142.58. 150.30, 150.55, 153.37, 155.47, 156.40, 157.51, 169.79.
  • 29
    • 55249083191 scopus 로고    scopus 로고
    • Yield: 28, Anal. Found: C, 40.75; H, 3.07; N, 9.79. Calcd for, Ru(OCH3)(pyca)(bpy)}2(μ-N)]PF6· 2H2O: C, 40.20; H, 3.37; N, 9.65. FAB-MS (m/z, 836 (M, PF6, IR: ν(Ru-N-Ru) 1017 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 3.48 (s, 6H, 6.89 (dd, J, 5.5 and 5.2 Hz. 2H, 7.07 (d, J, 5.5 Hz, 2H, 7.71 (dd, J, 7.8 and 5.5 Hz, 2H, 7.92 (d, J, 7.8 Hz, 2H, 8.00 (d, J, 5.2 Hz, 4H, 8.08-8.12 (m, 6H, 8.29 (dd, J, 7.8 and 7.8 Hz, 2H, 9.50 (d, J, 5.5 Hz, 2H, 9.98 (d, J, 5.2 Hz, 2H, 13C NMR CD3CN, δ 59.67, 118.20, 125.04, 125.09, 128.33, 128.51, 129.19, 130.72, 142.01, 142.14, 142.54, 150.40, 153.09, 155.27, 156.16, 156.98, 169.70
    • 3CN): δ 59.67, 118.20, 125.04, 125.09, 128.33, 128.51, 129.19, 130.72, 142.01, 142.14, 142.54, 150.40, 153.09, 155.27, 156.16, 156.98, 169.70.
  • 32
    • 55249097548 scopus 로고    scopus 로고
    • int = 0.048), R1 = 0.0635, wR2 = 0.2243 [I > 2σ(I)]. CCDC 688231.
    • int = 0.048), R1 = 0.0635, wR2 = 0.2243 [I > 2σ(I)]. CCDC 688231.
  • 37
    • 55249116659 scopus 로고    scopus 로고
    • +), 415 (M - Cl).
    • +), 415 (M - Cl).


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