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26
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55249123953
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-
Yield: 87, Anal. Found: C, 32.74; H, 2.04; N, 9.43. Calcd for [RuCl(NO)(pyca)(bpy)]PF6: C, 32.58; H, 2.05; N, 9.50. FAB-MS (m/z, 445 (M, PF6, IR (KBr, ν(NO) 1901 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 7.65 (dd, J, 5.8 and 5.8 Hz, 1H, 7.95 (dd, J, 5.8 and 5.8 Hz, 1H, 8.00 (d, J, 5.8 Hz, 1H, 8.07 (dd, J, 5.5 and 5.5 Hz, 1H, 8.20 (d, J, 7.8 Hz, 1H, 8.37-8.42 (m, 2H, 8.50 (dd, J, 8.2 and 7.6 Hz, 1H, 8.60 (dd, J, 8.2 and 8.2 Hz, 2H, 8.86 (d, J, 5.5 Hz, 1H, 9.47 (d, J, 5.5 Hz, 1H, 13C NMR CD3CN, δ 126.01, 126.10, 129.37, 129.44, 129.57, 132.36, 143.86, 144.31, 144.51, 149.97, 152.09, 152.40, 153.01, 155.98, 156.83, 178.51
-
3CN): δ 126.01, 126.10, 129.37, 129.44, 129.57, 132.36, 143.86, 144.31, 144.51, 149.97, 152.09, 152.40, 153.01, 155.98, 156.83, 178.51.
-
-
-
-
28
-
-
55249117385
-
-
Yield: 51, Anal. Found: C, 39.43; H, 3.61; N, 9.15. Calcd for, Ru(OC2H5)(pyca)(bpy)}2(μ-N)]PF 6·5H2O: C, 39.38; H, 4.04; N, 8.93. FAB-MS (m/z, 864 (M, PF6, 774 (M, PF6, 2OC 2H5, IR: ν(Ru-N-Ru) 1018 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 1.34 (dd, J, 6.9 and 6.9 Hz, 6H, 3.47 (dq, J, 9.2 and 6.9 Hz, 2H, 3.57 (dq, J, 9.2 and 6.9 Hz, 2H, 6.92 (dd, J, 5.5 and 5.5 Hz, 2H, 7.02 (d, J, 5.5 Hz, 2H, 7.81 (dd, J, 7.8 and 5.5 Hz, 2H, 7.94 (d, J, 7.8 Hz, 2H, 7.99-8.04 (m, 6H, 8.09 (d, J, 7.8 Hz, 2H, 8.15 (dd, J, 7.8 and 7.8 Hz, 2H, 8.27 (dd, J, 7.8 and 7.8 Hz, 2H, 9.64 (d, J, 5.5 Hz, 2H, 10.11 (d, J, 5.5 Hz, 2H, 13C NMR CD3CN, Me4Si, δ 21.03, 66.75, 125.17, 125.22, 128.39, 128
-
4Si): δ 21.03, 66.75, 125.17, 125.22, 128.39, 128.68, 129.35, 130.32, 142.10, 142.18, 142.58. 150.30, 150.55, 153.37, 155.47, 156.40, 157.51, 169.79.
-
-
-
-
29
-
-
55249083191
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-
Yield: 28, Anal. Found: C, 40.75; H, 3.07; N, 9.79. Calcd for, Ru(OCH3)(pyca)(bpy)}2(μ-N)]PF6· 2H2O: C, 40.20; H, 3.37; N, 9.65. FAB-MS (m/z, 836 (M, PF6, IR: ν(Ru-N-Ru) 1017 cm-1. 1H NMR (500 MHz, CD3CN, Me4Si, δ 3.48 (s, 6H, 6.89 (dd, J, 5.5 and 5.2 Hz. 2H, 7.07 (d, J, 5.5 Hz, 2H, 7.71 (dd, J, 7.8 and 5.5 Hz, 2H, 7.92 (d, J, 7.8 Hz, 2H, 8.00 (d, J, 5.2 Hz, 4H, 8.08-8.12 (m, 6H, 8.29 (dd, J, 7.8 and 7.8 Hz, 2H, 9.50 (d, J, 5.5 Hz, 2H, 9.98 (d, J, 5.2 Hz, 2H, 13C NMR CD3CN, δ 59.67, 118.20, 125.04, 125.09, 128.33, 128.51, 129.19, 130.72, 142.01, 142.14, 142.54, 150.40, 153.09, 155.27, 156.16, 156.98, 169.70
-
3CN): δ 59.67, 118.20, 125.04, 125.09, 128.33, 128.51, 129.19, 130.72, 142.01, 142.14, 142.54, 150.40, 153.09, 155.27, 156.16, 156.98, 169.70.
-
-
-
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30
-
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33847800665
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32
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55249097548
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int = 0.048), R1 = 0.0635, wR2 = 0.2243 [I > 2σ(I)]. CCDC 688231.
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int = 0.048), R1 = 0.0635, wR2 = 0.2243 [I > 2σ(I)]. CCDC 688231.
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33
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0000014164
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55249116659
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+), 415 (M - Cl).
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+), 415 (M - Cl).
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