Mechanism of the palladium-catalyzed carbohydroxylation of allene-substituted conjugated dienes: Rationalization of the recently observed nucleophilic attack by water on a (π-allyl)palladium intermediate

Chemistry - A European Journal

Volumn 14, Issue 30, 2008, Pages 9175-9180

  Karlsson, Erik A ^a   Bäckvall, Jan E ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

Density functional calculations; Homogeneous catalysis; Palladium; Water

Indexed keywords

COORDINATION REACTIONS; ORGANIC POLYMERS; PALLADIUM; POTENTIAL ENERGY; REACTION KINETICS; SULFUR COMPOUNDS;

ALLYL COMPLEXES; BENZOQUINONE; CONJUGATED DIENES; CYCLOHEXADIENE; DENSITY FUNCTIONAL CALCULATIONS; DFT CALCULATIONS; DOUBLE BONDS; HOMOGENEOUS CATALYSIS; NUCLEOPHILIC ATTACKS; PALLADIUM INTERMEDIATES; TRANSITION STATES; VINYL BONDS;

PALLADIUM COMPOUNDS;

EID: 55049133053     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801294     Document Type: Article

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