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54849412745
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Owing to the different electron binding energies and relative yields, the photoelectron spectrum of the iminodiazomethyl anion is virtually free from contributions from the other structural isomers present in the ion beam see ref 1
-
Owing to the different electron binding energies and relative yields, the photoelectron spectrum of the iminodiazomethyl anion is virtually free from contributions from the other structural isomers present in the ion beam (see ref 1).
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10
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0000592747
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21
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54849406510
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-1 to improve its matching with the observed peak position. The same adjustments have been made for all the conformers.
-
-1 to improve its matching with the observed peak position. The same adjustments have been made for all the conformers.
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22
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0000541688
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25
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54849432154
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There is no clear sign of the excited state in the photoelectron spectrum of the iminodiazomethyl anion even when a laser beam of 351.1 nm (3.531.eV) is used
-
There is no clear sign of the excited state in the photoelectron spectrum of the iminodiazomethyl anion even when a laser beam of 351.1 nm (3.531.eV) is used.
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26
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54849428484
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β nuclear framework, the second specification of the conformation is not meaningful for this excited state.
-
β nuclear framework, the second specification of the conformation is not meaningful for this excited state.
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27
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0001980554
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Koppel, H.; Domcke, W.; Cederbaum, L. S. Adv. Chem. Phys. 1984, 57, 59-246.
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54849430896
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β bending coordinate for the excited state of the (ZE)-radical at its equilibrium geometry.
-
β bending coordinate for the excited state of the (ZE)-radical at its equilibrium geometry.
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29
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33748252255
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54849439668
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See discussions in ref 1 for examples of anion-mediated triazole ring-fragmentation in solution.
-
See discussions in ref 1 for examples of anion-mediated triazole ring-fragmentation in solution.
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-
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36
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0037119339
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Vij, A.; Pavlovich, J. G.; Wilson, W. W.; Vij, V.; Christe, K. O. Angew. Chem., Int. Ed. 2002, 41, 3051-3054.
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38
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54849435207
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Fragmentation of the 1,2,3-triazolide ion to both the ketenimine anion and the cyanomethyl anion requires H migration.
-
Fragmentation of the 1,2,3-triazolide ion to both the ketenimine anion and the cyanomethyl anion requires H migration.
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39
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0037154717
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