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Volumn 112, Issue 40, 2008, Pages 9723-9730

Ion chemistry of 1H-1,2,3-triazole. 2. Photoelectron spectrum of the iminodiazomethyl anion and collision induced dissociation of the 1,2,3-triazolide ion

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONAL ISOMERIZATION; DFT CALCULATIONS; EQUILIBRIUM GEOMETRIES; HELIUM BUFFER GASSES; HYDROXIDE IONS; INDUCED DISSOCIATIONS; ION CHEMISTRIES; ISOMERIC IONS; NORMAL MODES; PHOTOELECTRON SPECTRUMS; RELATIVE ABUNDANCES; SELECTED ION FLOW TUBES; SPECTRAL ANALYSES; SPECTRAL SIMULATIONS; STRUCTURAL ISOMERS; STRUCTURE CALCULATIONS; VIBRONIC STRUCTURES;

EID: 54849436672     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp805023n     Document Type: Article
Times cited : (5)

References (41)
  • 9
    • 54849412745 scopus 로고    scopus 로고
    • Owing to the different electron binding energies and relative yields, the photoelectron spectrum of the iminodiazomethyl anion is virtually free from contributions from the other structural isomers present in the ion beam see ref 1
    • Owing to the different electron binding energies and relative yields, the photoelectron spectrum of the iminodiazomethyl anion is virtually free from contributions from the other structural isomers present in the ion beam (see ref 1).
  • 14
    • 9244241463 scopus 로고    scopus 로고
    • Flow Tubes
    • Theory and Ion Chemistry; Gross, M. L, Caprioli, R, Eds, Elsevier, Amsterdam
    • Bierbaum, V. M. Flow Tubes. In Theory and Ion Chemistry; Gross, M. L., Caprioli, R., Eds.; Encyclopedia of Mass Spectrometry, Vol. 1; Elsevier, Amsterdam, 2003; pp 98-109.
    • (2003) Encyclopedia of Mass Spectrometry , vol.1 , pp. 98-109
    • Bierbaum, V.M.1
  • 18
    • 54849412442 scopus 로고    scopus 로고
    • Frisch, M. J. et al. Gaussian 03, revision B.05, Gaussian, Inc.: Pittsburgh, PA, 2003.
    • Frisch, M. J. et al. Gaussian 03, revision B.05, Gaussian, Inc.: Pittsburgh, PA, 2003.
  • 21
    • 54849406510 scopus 로고    scopus 로고
    • -1 to improve its matching with the observed peak position. The same adjustments have been made for all the conformers.
    • -1 to improve its matching with the observed peak position. The same adjustments have been made for all the conformers.
  • 25
    • 54849432154 scopus 로고    scopus 로고
    • There is no clear sign of the excited state in the photoelectron spectrum of the iminodiazomethyl anion even when a laser beam of 351.1 nm (3.531.eV) is used
    • There is no clear sign of the excited state in the photoelectron spectrum of the iminodiazomethyl anion even when a laser beam of 351.1 nm (3.531.eV) is used.
  • 26
    • 54849428484 scopus 로고    scopus 로고
    • β nuclear framework, the second specification of the conformation is not meaningful for this excited state.
    • β nuclear framework, the second specification of the conformation is not meaningful for this excited state.
  • 28
    • 54849430896 scopus 로고    scopus 로고
    • β bending coordinate for the excited state of the (ZE)-radical at its equilibrium geometry.
    • β bending coordinate for the excited state of the (ZE)-radical at its equilibrium geometry.
  • 33
    • 54849439668 scopus 로고    scopus 로고
    • See discussions in ref 1 for examples of anion-mediated triazole ring-fragmentation in solution.
    • See discussions in ref 1 for examples of anion-mediated triazole ring-fragmentation in solution.
  • 38
    • 54849435207 scopus 로고    scopus 로고
    • Fragmentation of the 1,2,3-triazolide ion to both the ketenimine anion and the cyanomethyl anion requires H migration.
    • Fragmentation of the 1,2,3-triazolide ion to both the ketenimine anion and the cyanomethyl anion requires H migration.
  • 41


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.