Fabrication and characterization of fully dense Si-C-N ceramics from a poly(ureamethylvinyl)silazane precursor

Journal of the European Ceramic Society

Volumn 29, Issue 1, 2009, Pages 163-173

  Janakiraman, Narayanan ^a   Aldinger, Fritz ^a  

^a MAX PLANCK INSTITUTE FOR INTELLIGENT SYSTEMS   (Germany)

Author keywords

A. Precursors organic; B. Electron microscopy; B. Nanocomposites; B. Spectroscopy; Si C N

Indexed keywords

BUILDING MATERIALS; CERAMIC MATERIALS; CRYSTALLINE MATERIALS; FLUID MECHANICS; KNOWLEDGE BASED SYSTEMS; MECHANICAL PROPERTIES; SILICON;

A. PRECURSORS-ORGANIC; B. ELECTRON MICROSCOPY; B. NANOCOMPOSITES; B. SPECTROSCOPY; SI-C-N;

AMORPHOUS SILICON;

EID: 54849185500     PISSN: 09552219     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jeurceramsoc.2008.05.028     Document Type: Article

References (41)

1. Legrow G.E., Lim T.F., Lipowitz J., and Reaoch R.S. Ceramics from hydridopolysilazane. Am. Ceram. Soc. Bull. 66 (1987) 363-367
2. Chaim R., and Heuer A.H. Microstructural and microchemical characterization of silicon-carbide and silicon carbonitride ceramic fibers produced from polymer precursors. J. Am. Ceram. Soc. 71 (1988) 960-969
3. Motz G., Hacker J., and Ziegler G. Special modified silazanes for coatings, fibers and CMC's. Ceram. Eng. Sci. Proc. 21 (2000) 307-314
4. Motz G., and Ziegler G. Simple processibility of precursor-derived SiCN coatings by optimized precursors. Key Eng. Mater. 206-213 (2002) 475-478
5. Heimann D., Bill J., Aldinger F., Schanz P., Gern F., Krenkel W., et al. Development of oxidation protected carbon/carbon. Zeitschrift fuer Flugwissenchaften und Weltraumforschung 19 (1995) 180-188
6. Wagner S., Seifert H.J., and Aldinger F. High-temperature reactions of C/C-SiC composites with precursor-derived ceramic coatings. Mater. Manuf. Process. 17 (2002) 619-635
7. Lee, S. H., Processing of carbon fiber reinforced composites with particulate-filled precursor-derived Si-C-N matrix phases. PhD thesis, Stuttgart: Universität Stuttgart, 2004.
8. Liew L., Zhang W., Bright V.M., An L., Dunn M.L., and Raj R. Fabrication of SiCN ceramic MEMs using injectable polymer-precursor technique. Sens. Actuators 89 (2001) 64-70
9. Bill J., and Aldinger F. Precursor-derived covalent ceramics. Adv. Mater. 7 (1995) 775-787
10. Kroke E., Li Y., Konetschny C., Lecomte E., Fasel C., and Riedel R. Silazane derived ceramics and related materials. Mater. Sci. Eng. (R) 26 (2000) 97-199
11. Nishimura T., Haug R., Bill J., Thurn G., and Aldinger F. Mechanical and thermal properties of Si-C-N material from polyvinylsilazane. J. Mater. Sci. 33 (1998) 5237-5241
12. Galusek D., Riley F.L., and Riedel R. Nanoindentation of a polymer-derived amorphous silicon carbonitride ceramic. J. Am. Ceram. Soc. 84 (2001) 1164-1166
13. Bauer A., Christ M., Zimmermann A., and Aldinger F. Fracture toughness of amorphous precursor-derived ceramics in the silicon-carbon-nitrogen system. J. Am. Ceram. Soc. 84 (2001) 2203-2207
14. Seitz J., and Bill J. Production of compact polysilazane-derived Si/C/N-ceramics by plastic forming. J. Mater. Sci. Lett. 15 (1996) 391-393
15. Konetschny C., Galusek D., Reschke S., Fasel C., and Riedel R. Dense silicon carbonitride ceramics by pyrolysis of cross-linked and warm pressed polysilazane powders. J. Eur. Ceram. Soc. 19 (1999) 2789-2796
16. Galusek D., Reschke S., Konetschny C., and Riedel R. Si/C/N amorphous bulk ceramics by axial pressing of polyhydridomethylsilazane at elevated temperature. Silic. Ind. 63 (1998) 123-128
17. Wan J., Gasch M.J., and Mukherjee A.K. Silicon carbonitride ceramics produced by pyrolysis of polymer ceramic precursor. J. Mater. Res. 15 (2000) 1657-1660
18. Ishihara S., Gu H., Bill J., Aldinger F., and Wakai F. Densification of precursor-derived Si-C-N ceramics by high-pressure hot isostatic pressing. J. Am. Ceram. Soc. 85 (2002) 1706-1712
19. Freimuth H., Hessel V., Kölle H., Lacher M., Ehrfeld W., Vaahs T., et al. Formation of complex ceramic miniaturized structures by pyrolysis of poly(vinylsilazane). J. Am. Ceram. Soc. 79 (1996) 1457-1465
20. Shah S., and Raj R. Mechanical properties of a fully dense polymer derived ceramic made by a novel pressure casting process. Acta Mater. 50 (2002) 4093-4103
21. Maleki H., Holland L.R., Jenkins G.M., Zimmerman R.L., and Porter W. Maximum heating rates for producing undistorted glassy carbon ware determined by wedge-shaped samples. J. Mater. Res. 11 (1996) 2368-2375
22. Li Y., Riedel R., Steiger J., and Seggern H.V. Novel transparent polysilazane glass: synthesis and properties. Adv. Eng. Mater. 2 (2000) 290-293
23. Yao H., Kovenklioglu S., and Kalyon D.M. Pore formation in the pyrolysis of polymers to ceramics. Chem. Eng. Commun. 96 (1990) 155-175
24. Kalyon D.M., and Kovenklioglu S. Processibility of organometallic polymer precursors for non-oxide ceramic applications. Adv. Polym. Technol. 7 (1987) 191-199
25. Lewinsohn C.A., Colombo P., and Ünal O. Stresses occurring during joining of ceramics using preceramic polymers. J. Am. Ceram. Soc. 84 (2001) 2240-2244
26. Sorarù G.D., Dallapicolla E., and D'Andrea G. Mechanical characterization of sol-gel derived silicon oxycarbide glasses. J. Am. Ceram. Soc. 79 (1996) 2074-2080
27. 4. J. Non-Cryst. Solids 43 (1981) 7-15
28. Janakiraman N., Weinmann M., Schuhmacher J., Müller K., Bill J., Aldinger F., et al. Thermal stability, phase evolution, and crystallization in Si-B-C-N ceramics derived from a polyborosilazane precursor. J. Am. Ceram. Soc. 85 (2002) 1807-1814
29. Tuinstra F., and Koenig J.L. Raman spectrum of graphite. J. Chem. Phys. 53 (1970) 1126-1130
30. Ferrari A.C., and Robertson. Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon. J. Phys. Rev. B 64 (2001) 075414
31. Ferrari A.C., and Robertson. Interpretation of Raman spectra of disordered and amorphous carbon. J. Phys. Rev. B 61 (2000) 14095-14107
32. Nemanich R.J., and Solin S.A. 1st-order and 2nd-order Raman-scattering from finite-size crystals of graphite. Phys. Rev. B 20 (1979) 392-401
33. Wang Y., Alsmeyer D.C., and McCreery R.L. Raman-spectroscopy of carbon materials-structural basis of observed spectra. Chem. Mater. 2 (1990) 557-563
34. Haug, J., Untersuchung der Struktur und des Kristallisationsverhaltens von Si-C-N- und Si-B-C-N-Precursorkeramiken mit Röntgen und Neutronenbeugung. PhD thesis, Stuttgart: Universität Stuttgart, 2002.
35. Monthioux M., and Delverdier O. Thermal behavior of (organosilicon) polymer-derived ceramics 5. Main facts and trends. J. Eur. Ceram. Soc. 16 (1996) 721-737
36. Gregori G., Kleebe H.J., Brequel H., Enzo S., and Ziegler G. Microstructure evolution of precursors-derived SiCN ceramics upon thermal treatment between 1000 and 1400 °C. J. Non-Cryst. Solids 351 (2005) 1393-1402
37. Turquat C., Kleebe H.J., Gregori G., Walter S., and Soraru G.D. Transmission electron microscopy and electron energy-loss spectroscopy study of nonstoichiometric silicon-carbon-oxygen glasses. J. Am. Ceram. Soc. 84 (2001) 2189-2196
38. Li Y., Kroke E., Riedel R., Fasel C., Gervais C., and Babonneau F. Thermal cross-linking and pyrolytic conversion of poly(ureamethylvinyl)silazanes to silicon-based ceramics. Appl. Organometall. Chem. 15 (2001) 820-832
39. Bauer, A., Einfluss der Herstellungsparameter auf die mechanischen Eigenschaften von Si-(B-)C-N-Precursorkeramiken. PhD thesis, Stuttgart: Universität Stuttgart, 2002.
40. Kroll P. Modeling the 'free carbon' phase in amorphous silicon oxycarbide. J. Non-Cryst. Solids 351 (2005) 1121-1126
41. z-ceramics derived from polyvinylsilazane. J. Eur. Ceram. Soc. 23 (2003) 781-789