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For diverted total synthesis of natural products, see:
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0000159355
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Suzuki-Miyaura reaction of a related imidazolyl boronic acid has been reported to be unsuccessful in the synthesis of topsentin, see:
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Suzuki-Miyaura reaction of a related imidazolyl boronic acid has been reported to be unsuccessful in the synthesis of topsentin, see:. Kawasaki I., Katsuma H., Nakayama Y., Yamashita M., and Ohta S. Heterocycles 48 (1998) 1887-1901
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14
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54449100609
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note
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The synthesis of 13 will be published in a full account of this work.
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23
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33750283011
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24
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54449094398
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note
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1H NMR spectrum, since the coupling product 15 was contaminated with small quantities of reactants, which could not be completely removed by chromatographic purification.
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