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The difference in binding energy compared with that in Figure 4a (0.25 eV) is most likely the result of an iron-induced work function shift. After heating to 550 R (Figure 6b,c), the peaks assume the same positions as in the case of Fe postadsorption.
-
The difference in binding energy compared with that in Figure 4a (0.25 eV) is most likely the result of an iron-induced work function shift. After heating to 550 R (Figure 6b,c), the peaks assume the same positions as in the case of Fe postadsorption.
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3/2 levels (∼1087 eV and ̊778 eV, respectively) lead to slightly different probe depths for nitrogen and iron (with a larger probe depth for nitrogen). These differences, which are neglected in our comparison of the peak intensities, may slightly affect the numbers reported.
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