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M. J. Ingleson, M. Pink, J. C. Huffman, H. Fan, K. G. Caulton, Organometallics 2006, 25, 1112-1119. The values given for the nitrogen hyperfine coupling (A = 0,0,160) G in this paper are unrealistic. The spin population was determined by DFT calculations.
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85153183907
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+ complexes: a) P. Maire, T. Büttner, F. Breher, P. Le Floch, H. Grützmacher, Angew. Chem. 2005, 117, 6477;
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85153317901
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It is well established that the equatorial position in TBP 18-electron complexes is labile (see standard textbooks on organometallic chemistry). Furthermore, for electronic reasons π-acceptor ligands bind in the equatorial position, whereas σ-donor ligands reside in the axial position of TBP; for a classical paper, see: A. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
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It is well established that the equatorial position in TBP 18-electron complexes is labile (see standard textbooks on organometallic chemistry). Furthermore, for electronic reasons π-acceptor ligands bind in the equatorial position, whereas σ-donor ligands reside in the axial position of TBP; for a classical paper, see: A. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
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29
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85153194858
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For an extensive listing of pKa values of various acids see: D. A. Ripin, D. A. Evans, http://evans.harvard.edu/pdf/evans_pKa_Table.pdf.
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For an extensive listing of pKa values of various acids see: D. A. Ripin, D. A. Evans, http://evans.harvard.edu/pdf/evans_pKa_Table.pdf.
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a) P. Maire, F. Breher, H. Schönberg, H. Grützmacher, Organometallics 2005, 24, 3207;
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T. Büttner, Synthesis and Reactivity of Penta Coordinated Rhodium Amine-Diolefin Complexes, ETH dissertation No. 15503, 2004. Available through the internet under http://ecollection.ethbib.ethz.ch/show? type=diss&nr=15503.
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A slight improvement in the simulation intensities is obtained by including a nuclear quadrupole coupling |e2qQ/h| ≈ 30 MHz
-
2qQ/h| ≈ 30 MHz.
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43
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85153212961
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+ may have been converted into the NH complex with trace amounts of water.
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+ may have been converted into the NH complex with trace amounts of water.
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44
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