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Volumn , Issue 30, 2008, Pages 4691-4703

Rhodium and iridium amino, amido, and aminyl radical complexes

Author keywords

Cyclic voltammetry; Iridium; Organometallic compounds; Phosphanes; Reaction mechanisms; Rhodium

Indexed keywords

COORDINATION REACTIONS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; IRIDIUM COMPOUNDS; ORGANOMETALLICS; RHODIUM COMPOUNDS;

EID: 54149114126     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800702     Document Type: Article
Times cited : (24)

References (54)
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    • M. J. Ingleson, M. Pink, J. C. Huffman, H. Fan, K. G. Caulton, Organometallics 2006, 25, 1112-1119. The values given for the nitrogen hyperfine coupling (A = 0,0,160) G in this paper are unrealistic. The spin population was determined by DFT calculations.
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    • + complexes: a) P. Maire, T. Büttner, F. Breher, P. Le Floch, H. Grützmacher, Angew. Chem. 2005, 117, 6477;
    • + complexes: a) P. Maire, T. Büttner, F. Breher, P. Le Floch, H. Grützmacher, Angew. Chem. 2005, 117, 6477;
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    • It is well established that the equatorial position in TBP 18-electron complexes is labile (see standard textbooks on organometallic chemistry). Furthermore, for electronic reasons π-acceptor ligands bind in the equatorial position, whereas σ-donor ligands reside in the axial position of TBP; for a classical paper, see: A. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
    • It is well established that the equatorial position in TBP 18-electron complexes is labile (see standard textbooks on organometallic chemistry). Furthermore, for electronic reasons π-acceptor ligands bind in the equatorial position, whereas σ-donor ligands reside in the axial position of TBP; for a classical paper, see: A. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365.
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    • For an extensive listing of pKa values of various acids see: D. A. Ripin, D. A. Evans, http://evans.harvard.edu/pdf/evans_pKa_Table.pdf.
    • For an extensive listing of pKa values of various acids see: D. A. Ripin, D. A. Evans, http://evans.harvard.edu/pdf/evans_pKa_Table.pdf.
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    • T. Büttner, Synthesis and Reactivity of Penta Coordinated Rhodium Amine-Diolefin Complexes, ETH dissertation No. 15503, 2004. Available through the internet under http://ecollection.ethbib.ethz.ch/show? type=diss&nr=15503.
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    • A slight improvement in the simulation intensities is obtained by including a nuclear quadrupole coupling |e2qQ/h| ≈ 30 MHz
    • 2qQ/h| ≈ 30 MHz.
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    • + may have been converted into the NH complex with trace amounts of water.
    • + may have been converted into the NH complex with trace amounts of water.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.