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Volumn 14, Issue 22, 2008, Pages 6742-6753

Reactivity of molecular dioxygen towards a series of isostructural dichloroiron(III) complexes with tripodal tetraamine ligands: General access to μ-oxodiiron(III) complexes and effect of α-fluorination on the reaction kinetics

Author keywords

Iron; Kinetics; N ligands; Oxo ligands; Tripodal ligands

Indexed keywords

AMINES; CHEMICAL REACTIONS; FLUORINE; ORGANIC COMPOUNDS; REACTION KINETICS;

EID: 53949117392     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701967     Document Type: Article
Times cited : (28)

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    • A particular case of square-pyramidal geometry has been observed in the solid state as a result of stacking effects with a tripod substituted by a potentially coordinating ligand: N. K. Thallaj, A. Machkour. D. Mandon, R. Welter, New J. Chem. 2005, 29, 1555-1558
    • A particular case of square-pyramidal geometry has been observed in the solid state as a result of stacking effects with a tripod substituted by a potentially coordinating ligand: N. K. Thallaj, A. Machkour. D. Mandon, R. Welter, New J. Chem. 2005, 29, 1555-1558.
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    • 3CN, in which the structures are retained in solution), the use of a strongly dissociating medium (e.g., a 0.1 M solution of supporting electrolyte) leads to dissociation and aggregation of the complexes, since multiple waves are detected at positive potential.
    • 3CN, in which the structures are retained in solution), the use of a strongly dissociating medium (e.g., a 0.1 M solution of supporting electrolyte) leads to dissociation and aggregation of the complexes, since multiple waves are detected at positive potential.
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    • This hypothesis is supported by the following experimental facts: working in non-dissociating solvents such as CH2Cl2 decreases the reaction rate by a factor of ten; also, freezing the chloride ions at the metal site by hydrogen bonding with an α-amido-substituted ligand impedes the oxygenation reaction: L. Benhamou, H. Jaafar, A. Wane. D. Mandon, unpublished results
    • 2 decreases the reaction rate by a factor of ten; also, "freezing" the chloride ions at the metal site by hydrogen bonding with an α-amido-substituted ligand impedes the oxygenation reaction: L. Benhamou, H. Jaafar, A. Wane. D. Mandon, unpublished results.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.