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1
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34548769048
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Abbreviations: methyl-coenzyme M (methyl-SCoM, 2-(methylthio, ethanesulfonic acid; coenzyme B CoBSH, N-7-mercaptoheptanoyl-threonine phosphate; ENDOR, electron nuclear double resonance; mass spectrometry, MS
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Abbreviations: methyl-coenzyme M (methyl-SCoM), 2-(methylthio)- ethanesulfonic acid; coenzyme B (CoBSH), N-7-mercaptoheptanoyl-threonine phosphate; ENDOR, electron nuclear double resonance; mass spectrometry, MS.
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2
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0030726657
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(a) Signer, L.; Knuppe, C.; Hug, R.; Schweizer, B.; Pfaltz, A.; Jaun, B. Chem.-Eur. J. 2000, 6, 3508-3516.
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6
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0035946914
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(b) Grabarse, W. G.; Mahlert, F.; Duin, E. C.; Goubeaud, M.; Shima, S.; Thauer, R. K.; Lamzin, V.; Ermler, U. J. Mol. Biol. 2001, 309, 315-330.
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Crabtree, R.H.4
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9
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Harmer, J.6
Jaun, B.7
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4644265740
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Goenrich, M.1
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Thauer, R.K.6
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33749362261
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Kunz, R.C.1
Horng, Y.-C.2
Ragsdale, S.W.3
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13
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34548783025
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3I in 50 mM Tris-HCl, pH 7.6.
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3I in 50 mM Tris-HCl, pH 7.6.
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15
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34548717359
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35 GHz EPR/ENDOR instrumentation and ENDOR analysis procedures have been described in ref 15.
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35 GHz EPR/ENDOR instrumentation and ENDOR analysis procedures have been described in ref 15.
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16
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33746918356
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Lees, N. S.; Chen, D.; Walsby, C. J.; Behshad, E.; Frey, P. A.; Hoffman, B. M. J. Am. Chem. Soc. 2006, 128, 10145-10154.
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Lees, N.S.1
Chen, D.2
Walsby, C.J.3
Behshad, E.4
Frey, P.A.5
Hoffman, B.M.6
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17
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0034639453
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Telser, J.; Horng, Y.-C.; Becker, D. F.; Hoffman, B. M.; Ragsdale, S. W. J. Am. Chem. Soc. 2000, 122, 182-183.
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Telser, J.1
Horng, Y.-C.2
Becker, D.F.3
Hoffman, B.M.4
Ragsdale, S.W.5
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18
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29344456172
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Harmer, J.; Finazzo, C.; Piskorski, R.; Bauer, C.; Jaun, B.; Duin, E. C.; Goenrich, M.; Thauer, R. K.; Van Doorslaer, S.; Schweiger, A. J. Am. Chem. Soc. 2005, 127, 17744-17755.
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Harmer, J.1
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Goenrich, M.7
Thauer, R.K.8
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Schweiger, A.10
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19
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34548769593
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Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications; John Wiley & Sons, Inc: New York, 1994; Table G.4.
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Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications; John Wiley & Sons, Inc: New York, 1994; Table G.4.
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21
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34548772108
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The appearance of well-resolved doublets is shown to result from Mims hyperfine suppression in the vicinity of the deuteron Larmor frequency Figure S2, Supporting Information
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The appearance of well-resolved doublets is shown to result from Mims hyperfine suppression in the vicinity of the deuteron Larmor frequency (Figure S2, Supporting Information).
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22
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3543112704
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Lee, H.-I.; Igarashi, R. Y.; Laryukhin, M.; Doan, P. E.; Dos Santos, P. C.; Dean, D. R.; Seefeldt, L. C.; Hoffman, B. M. J. Am. Chem. Soc. 2004, 126, 9563-9569.
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Epel, B.1
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Craft, J. L.; Horng, Y.-C.; Ragsdale, S. W.; Brunold, T. C. J. Am. Chem. Soc. 2004, 126, 4068-4069.
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Craft, J.L.1
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Manikandan, P.; Choi, E.-Y.; Hille, R.; Hoffman, B. M. J. Am. Chem. Soc. 2001, 123, 2658-2663.
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