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Volumn 350, Issue 13, 2008, Pages 2013-2023

A new class of 3′-sulfonyl binaphos ligands: Modulation of activity and selectivity in asymmetric palladium-catalysed hydrophosphorylation of styrene

Author keywords

Asymmetric catalysis; BINOL; Hydrophosphination; Palladium; Phosphines; Phosphites

Indexed keywords


EID: 53849117474     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200800366     Document Type: Article
Times cited : (47)

References (51)
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    • For recent reviews and accounts of transition metal-catalysed asymmetric hydrosilylation see: a
    • For recent reviews and accounts of transition metal-catalysed asymmetric hydrosilylation see: a) A. K. Roy, Adv. Organometal. Chem. 2008, 55, 1-59;
    • (2008) Adv. Organometal. Chem , vol.55 , pp. 1-59
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    • 18244395541 scopus 로고    scopus 로고
    • For recent reviews and accounts of transition metal-catalysed asymmetric hydroboration see: a
    • For recent reviews and accounts of transition metal-catalysed asymmetric hydroboration see: a) A. M. Carroll, T. P. O'Sulivan, P. J. Guiry, Adv. Synth. Catal. 2005, 347, 609-631;
    • (2005) Adv. Synth. Catal , vol.347 , pp. 609-631
    • Carroll, A.M.1    O'Sulivan, T.P.2    Guiry, P.J.3
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    • ref.[8c];
    • [8c];
  • 40
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    • The mechanism of the reaction appears to involve generation of an aryl anion (rather than aryllithium) intermediate, see: A. M. Dyke, D. M. Gill, J. N. Harvey, A. J. Hester, G. C. Lloyd-Jones, M. P. Munoz, I. R. Shepperson, Angew. Chem. Int. Ed. 2008, 47, 5067-5070.
    • The mechanism of the reaction appears to involve generation of an aryl anion (rather than aryllithium) intermediate, see: A. M. Dyke, D. M. Gill, J. N. Harvey, A. J. Hester, G. C. Lloyd-Jones, M. P. Munoz, I. R. Shepperson, Angew. Chem. Int. Ed. 2008, 47, 5067-5070.
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    • 0038676302 scopus 로고    scopus 로고
    • for an alternative highly enantioselective naphthyl-naphthyl coupling route to 3-sulfonyl
    • b) for an alternative highly enantioselective naphthyl-naphthyl coupling route to 3-sulfonyl BINOLs, see: X. Li, B. Hewgley, C. A. Mulrooney, J. Yang, M. C. Kozlowski, J. Org. Chem. 2003, 68, 5500 - 5511;
    • (2003) J. Org. Chem , vol.68 , pp. 5500-5511
    • BINOLs1    see2    Li, X.3    Hewgley, B.4    Mulrooney, C.A.5    Yang, J.6    Kozlowski, M.C.7
  • 43
    • 33646506378 scopus 로고    scopus 로고
    • for the preparation of 6,6′-bis(trifluoromethanesulfonyl)-1, 1′-BINOL, see: O. Mouhtady, H. Gaspard-Iloughmane, A. Laporterie, C. Le Roux, Tetrahedron Lett. 2006, 47, 4125-4128.
    • c) for the preparation of 6,6′-bis(trifluoromethanesulfonyl)-1, 1′-BINOL, see: O. Mouhtady, H. Gaspard-Iloughmane, A. Laporterie, C. Le Roux, Tetrahedron Lett. 2006, 47, 4125-4128.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.