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For addition of organolithium reagents to α-(trifluoromethyl) styrenes, see: a
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For addition of organolithium reagents to α-(trifluoromethyl) styrenes, see: a) R. Fontanelli, D. Sianesi, Ann. Chim. (Roma) 1965, 55, 862.
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For β-fluoride elimination of transition-metal complexes, see: [Rh]: a A. A. Peterson, K. McNeill, Organometallics 2006, 25, 4938.
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For β-fluoride elimination of transition-metal complexes, see: [Rh]: a) A. A. Peterson, K. McNeill, Organometallics 2006, 25, 4938.
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0001096111
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For other synthetic methods of gem-difluoroalkenes, see: a J. Ichikawa, J. Fluorine Chem. 2000, 105, 257.
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For other synthetic methods of gem-difluoroalkenes, see: a) J. Ichikawa, J. Fluorine Chem. 2000, 105, 257.
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0141654012
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and references therein
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b) J. Ichikawa, H. Fukui, Y. Ishibashi, J. Org. Chem. 2003, 68, 7800, and references therein.
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M. Lautens, A. Roy, K. Fukuoka, K. Fagnou, B. Martín-Matute, J. Am. Chem. Soc. 2001, 123, 5358.
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53649105121
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No reaction took place when the substrate 1a was heated with phenylboronic ester and methylmagnesium chloride in the absence of a rhodium catalyst. Other Grignard reagents such as methylmagnesium bromide and iodide gave lower yields.
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No reaction took place when the substrate 1a was heated with phenylboronic ester and methylmagnesium chloride in the absence of a rhodium catalyst. Other Grignard reagents such as methylmagnesium bromide and iodide gave lower yields.
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23
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15744385464
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a) J. Terao, H. Watabe, N. Kambe, J. Am. Chem. Soc. 2005, 127, 3656.
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29844439845
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b) N. Yoshikai, H. Mashima, E. Nakamura, J. Am. Chem. Soc. 2005, 127, 17978.
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Yoshikai, N.1
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53649093666
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For a reaction of lithium methyl(phenyl)borates generated from phenylboronic esters and
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For a reaction of lithium methyl(phenyl)borates generated from phenylboronic esters and MeLi, see: Y. Kobayashi, R. Mizojiri, E. Ikeda, J. Org. Chem. 1996, 67, 5391.
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J. Org. Chem
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MeLi1
see2
Kobayashi, Y.3
Mizojiri, R.4
Ikeda, E.5
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26
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0036761922
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The geometrical configurations of fluoroalkenes were assigned based upon a previous paper: R. Ocampo, W. R. Dolbier, Jr., F. Zuluaga, Collect. Czech. Chem. Commun. 2002, 67, 1325.
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The geometrical configurations of fluoroalkenes were assigned based upon a previous paper: R. Ocampo, W. R. Dolbier, Jr., F. Zuluaga, Collect. Czech. Chem. Commun. 2002, 67, 1325.
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53649108393
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Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/ index.html.
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Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/ index.html.
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