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Volumn 37, Issue 9, 2008, Pages 1006-1007

Synthesis of gem-difluoroalkenes via β-fluoride elimination of organorhodium(I)

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EID: 53649101811     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2008.1006     Document Type: Article
Times cited : (106)

References (27)
  • 1
    • 0037243669 scopus 로고    scopus 로고
    • For reviews, see: a
    • For reviews, see: a) K. Fagnou, M. Lautens, Chem. Rev. 2003, 103, 169.
    • (2003) Chem. Rev , vol.103 , pp. 169
    • Fagnou, K.1    Lautens, M.2
  • 12
    • 0342859669 scopus 로고
    • For addition of organolithium reagents to α-(trifluoromethyl) styrenes, see: a
    • For addition of organolithium reagents to α-(trifluoromethyl) styrenes, see: a) R. Fontanelli, D. Sianesi, Ann. Chim. (Roma) 1965, 55, 862.
    • (1965) Ann. Chim. (Roma) , vol.55 , pp. 862
    • Fontanelli, R.1    Sianesi, D.2
  • 14
    • 33750364962 scopus 로고    scopus 로고
    • For β-fluoride elimination of transition-metal complexes, see: [Rh]: a A. A. Peterson, K. McNeill, Organometallics 2006, 25, 4938.
    • For β-fluoride elimination of transition-metal complexes, see: [Rh]: a) A. A. Peterson, K. McNeill, Organometallics 2006, 25, 4938.
  • 19
    • 0001096111 scopus 로고    scopus 로고
    • For other synthetic methods of gem-difluoroalkenes, see: a J. Ichikawa, J. Fluorine Chem. 2000, 105, 257.
    • For other synthetic methods of gem-difluoroalkenes, see: a) J. Ichikawa, J. Fluorine Chem. 2000, 105, 257.
  • 22
    • 53649105121 scopus 로고    scopus 로고
    • No reaction took place when the substrate 1a was heated with phenylboronic ester and methylmagnesium chloride in the absence of a rhodium catalyst. Other Grignard reagents such as methylmagnesium bromide and iodide gave lower yields.
    • No reaction took place when the substrate 1a was heated with phenylboronic ester and methylmagnesium chloride in the absence of a rhodium catalyst. Other Grignard reagents such as methylmagnesium bromide and iodide gave lower yields.
  • 25
    • 53649093666 scopus 로고    scopus 로고
    • For a reaction of lithium methyl(phenyl)borates generated from phenylboronic esters and
    • For a reaction of lithium methyl(phenyl)borates generated from phenylboronic esters and MeLi, see: Y. Kobayashi, R. Mizojiri, E. Ikeda, J. Org. Chem. 1996, 67, 5391.
    • (1996) J. Org. Chem , vol.67 , pp. 5391
    • MeLi1    see2    Kobayashi, Y.3    Mizojiri, R.4    Ikeda, E.5
  • 26
    • 0036761922 scopus 로고    scopus 로고
    • The geometrical configurations of fluoroalkenes were assigned based upon a previous paper: R. Ocampo, W. R. Dolbier, Jr., F. Zuluaga, Collect. Czech. Chem. Commun. 2002, 67, 1325.
    • The geometrical configurations of fluoroalkenes were assigned based upon a previous paper: R. Ocampo, W. R. Dolbier, Jr., F. Zuluaga, Collect. Czech. Chem. Commun. 2002, 67, 1325.
  • 27
    • 53649108393 scopus 로고    scopus 로고
    • Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/ index.html.
    • Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/ index.html.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.