-
1
-
-
0000185390
-
-
a) K. A. Horn, Chem. Rev. 1995, 95, 1317-1350;
-
(1995)
Chem. Rev
, vol.95
, pp. 1317-1350
-
-
Horn, K.A.1
-
4
-
-
0034245863
-
-
d) R. Zimmer, C. U. Dinesh, E. Nandanan, F. A. Khan, Chem. Rev. 2000, 100, 3067-3312;
-
(2000)
Chem. Rev
, vol.100
, pp. 3067-3312
-
-
Zimmer, R.1
Dinesh, C.U.2
Nandanan, E.3
Khan, F.A.4
-
10
-
-
0000595175
-
-
b) I. Fleming, A. Barbero, D. Walter, Chem. Rev. 1997, 97, 2063-2192.
-
(1997)
Chem. Rev
, vol.97
, pp. 2063-2192
-
-
Fleming, I.1
Barbero, A.2
Walter, D.3
-
11
-
-
0001205903
-
-
M. Suginome, T. Matsuda, T. Yoshimoto, Y. Ito, Org. Lett. 1999, 1, 1567-1569.
-
(1999)
Org. Lett
, vol.1
, pp. 1567-1569
-
-
Suginome, M.1
Matsuda, T.2
Yoshimoto, T.3
Ito, Y.4
-
13
-
-
0038001941
-
-
T. Sagawa, Y. Asano, F. Ozawa, Organometallics 2002, 21, 5879-5886.
-
(2002)
Organometallics
, vol.21
, pp. 5879-5886
-
-
Sagawa, T.1
Asano, Y.2
Ozawa, F.3
-
14
-
-
85153232163
-
-
0 complexes in oxidative addition to aryl halides, see: a C. Amatore, M. Azzabi, A. Jutand, J. Am. Chem. Soc. 1991, 113, 8375-8384;
-
0 complexes in oxidative addition to aryl halides, see: a) C. Amatore, M. Azzabi, A. Jutand, J. Am. Chem. Soc. 1991, 113, 8375-8384;
-
-
-
-
15
-
-
0037765113
-
-
b) J. Pytkowicz, S. Roland, P. Mangeney, G. Meyer, A. Jutand, J. Organomet. Chem. 2003, 678, 166-179;
-
(2003)
J. Organomet. Chem
, vol.678
, pp. 166-179
-
-
Pytkowicz, J.1
Roland, S.2
Mangeney, P.3
Meyer, G.4
Jutand, A.5
-
19
-
-
0001234843
-
-
c) J. P. Birk, J. Halpern, A. L. Pickard, J. Am. Chem. Soc. 1968, 90, 4491-4492.
-
(1968)
J. Am. Chem. Soc
, vol.90
, pp. 4491-4492
-
-
Birk, J.P.1
Halpern, J.2
Pickard, A.L.3
-
22
-
-
85153195232
-
-
2Ph) of unidentified products.
-
2Ph) of unidentified products.
-
-
-
-
23
-
-
85153226203
-
-
1H NMR spectroscopy at 24 h intervals. After 6 d, a 0.54:0.62:0.35:0.62 mixture of 1/2/3/4 was obtained.
-
1H NMR spectroscopy at 24 h intervals. After 6 d, a 0.54:0.62:0.35:0.62 mixture of 1/2/3/4 was obtained.
-
-
-
-
24
-
-
85153177774
-
-
After 24 h at 80 °C, no trace of complexes 2-4 was present. No product of silaboration (5) was found.
-
After 24 h at 80 °C, no trace of complexes 2-4 was present. No product of silaboration (5) was found.
-
-
-
-
25
-
-
85153290272
-
-
Crystallization from Et2O, benzene, DCM, or CDCl3 with hexane or pentane was attempted by direct precipitation, diffusion chamber, or diffusion in the NMR tube. Typically, a brown oil was obtained, or complex 3 was isolated in pure form. Further attempts to isolate complex 4 were also made, but met with little success: reaction conditions were optimized in terms of stoichiometries, order and time of addition, and temperature, but no increase in the yield of 4 relative to that obtained under the standard conditions was observed. Exchange of Pt(acac)2 for Pt(cod)2 or addition of 1,3-cyclohexadiene to complex 2 isolated in pure form did not lead to any increase in amount or purity of complex 4. Finally, attempts to react 4 with sodium dimethyl malonate (A. J. Blacker, M. L. Clarke, M. S. Loft, M. F. Mahon, M. E. Humphries, J. M. J. Williams, Chem. Eur. J. 2000, 6, 353-360) met with n
-
2 or addition of 1,3-cyclohexadiene to complex 2 isolated in pure form did not lead to any increase in amount or purity of complex 4. Finally, attempts to react 4 with sodium dimethyl malonate (A. J. Blacker, M. L. Clarke, M. S. Loft, M. F. Mahon, M. E. Humphries, J. M. J. Williams, Chem. Eur. J. 2000, 6, 353-360) met with no success - heating at 60 ° C overnight only led to decomposition.
-
-
-
-
26
-
-
0034295260
-
-
M. Suginome, T. Matsuda, Y. Ito, Organometallics 2000, 19, 4647-4649.
-
(2000)
Organometallics
, vol.19
, pp. 4647-4649
-
-
Suginome, M.1
Matsuda, T.2
Ito, Y.3
|