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Volumn 47, Issue 17, 2008, Pages 3174-3179

Shaping of a conformationally flexible molecular structure for spectroscopy

Author keywords

Conformational flexibility; Laser spectroscopy; Molecular devices; Molecular modeling; Rotaxanes

Indexed keywords

CHEMICAL REACTIONS; MOLDS; PHOTORESISTS; PULSED LASER APPLICATIONS; QUANTUM CHEMISTRY;

EID: 53549089305     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200705627     Document Type: Article
Times cited : (31)

References (24)
  • 10
    • 26944493106 scopus 로고    scopus 로고
    • J. Berná J, D. A. Leigh, M. Lubomska, S. M. Mendoza, E. M. Pérez, P. Rudolf, G. Teobaldi, F. Zerbetto, Nat. Mater. 2005, 4, 704-710.
    • J. Berná J, D. A. Leigh, M. Lubomska, S. M. Mendoza, E. M. Pérez, P. Rudolf, G. Teobaldi, F. Zerbetto, Nat. Mater. 2005, 4, 704-710.
  • 21
    • 53549116924 scopus 로고    scopus 로고
    • The photoionization mass spectra in Figure 4a and b show a number of small but broad peaks. These peaks derive from minor fragmentation of ions in the flight tube after ionization of the rotaxane, and can thus not be directly related to the m/z ratio on the x axis.
    • The photoionization mass spectra in Figure 4a and b show a number of small but broad peaks. These peaks derive from minor fragmentation of ions in the flight tube after ionization of the rotaxane, and can thus not be directly related to the m/z ratio on the x axis.
  • 22
    • 53549105170 scopus 로고    scopus 로고
    • Optimization of the desorption conditions primarily involves the reduction of the power of the desorption laser and adjusting the position of the sample bar with respect to the nozzle. Although fine-tuning these parameters leads to a reduction of the width of the resonances, it reduces at the same time considerably the signal-to-noise ratio of the signal, and thus leads to extensive signal averaging
    • Optimization of the desorption conditions primarily involves the reduction of the power of the desorption laser and adjusting the position of the sample bar with respect to the nozzle. Although fine-tuning these parameters leads to a reduction of the width of the resonances, it reduces at the same time considerably the signal-to-noise ratio of the signal, and thus leads to extensive signal averaging.
  • 24
    • 4544231480 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 3260-3264.
    • (2004) Angew. Chem. Int. Ed , vol.43 , pp. 3260-3264


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.