Aryl halide tolerated electrophilic amination of arylboronic acids with N-chloroamides catalyzed by CuCl at room temperature

Angewandte Chemie - International Edition

Volumn 47, Issue 34, 2008, Pages 6414-6417

  He, Chuan ^a   Chen, Chong ^a   Cheng, Jin ^a   Liu, Chao ^a   Liu, Wei ^a   Li, Qiang ^a   Lei, Aiwen ^a  

^a WUHAN UNIVERSITY   (China)

Author keywords

Amides; Amination; Copper; Cross coupling; Homogeneous catalysis

Indexed keywords

ACIDS; AMINES; CHEMICAL REACTIONS; COPPER COMPOUNDS;

AMIDES; COPPER; CROSS-COUPLING; HOMOGENEOUS CATALYSIS;

AMINATION;

EID: 53349121032     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801427     Document Type: Article

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58. The excess of N-haloamides to arylboronic acids was to improve the conversion of arylboronic acids. The side products detected were mainly dechlorinated amides. The screening experiments (see the Supporting Information) revealed that when the ratio between 2a and 1c was lowered to 1.3:1, the yield decreased by about 10%.
59. II-mediated oxidative coupling (Chan-Lam-Evans procedure and one of modified procedures), and the yields of the latter were lower (see the Supporting Information).