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Volumn , Issue 24, 2008, Pages 3765-3768

Deaggregation of trimethylsilylmethyllithium

Author keywords

Aggregation; Carbanions; Lithium; N ligands; X ray diffraction

Indexed keywords

DIMERS; LIGANDS; LITHIUM; LITHIUM COMPOUNDS; SILICON COMPOUNDS;

EID: 53249156391     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800610     Document Type: Article
Times cited : (35)

References (47)
  • 3
    • 0037503118 scopus 로고    scopus 로고
    • Lead Structures in Lithium Organic Chemistry
    • Eds, Z. Rappoport, I. Marek, John Wiley & Sons, Chichester
    • b) T. Stey, D. Stalke, "Lead Structures in Lithium Organic Chemistry" in The Chemistry of Organolithium Compounds (Eds.: Z. Rappoport, I. Marek), John Wiley & Sons, Chichester, 2004.
    • (2004) The Chemistry of Organolithium Compounds
    • Stey, T.1    Stalke, D.2
  • 10
    • 0003872342 scopus 로고    scopus 로고
    • Organolithium Compounds - Industrial Applications and Handling
    • Ed, M. Schlosser, Wiley, New York
    • b) F. Totter, P. Rittmeyer, "Organolithium Compounds - Industrial Applications and Handling" in Organometallics in Synthesis: A Manual (Ed.: M. Schlosser), Wiley, New York, 2002.
    • (2002) Organometallics in Synthesis: A Manual
    • Totter, F.1    Rittmeyer, P.2
  • 24
    • 85163240823 scopus 로고    scopus 로고
    • Single-crystal structural analysis of 2-4: The data sets were collected on a Bruker Smart Apex II with a D8 goniometer (2, 3) or a Bruker TXS rotating anode with INCOATEC Mo-mirror optics, Apex II detector and D8 goniometer (4) from oil-coated, shock-cooled crystals[12, Mo-Kα λ, 71.073 pm, The integration was performed with SAINT V7.34A [V7.46A (3, which was followed by an empirical absorption correction with SADABS-2004/1 [SADABS-2007/5(3, The structures were solved by direct methods and refined with SHELXL against F2.[26] 2: C20H54Li 2N4Si2, M, 420.74 gmol-1, crystal size 0.5 X 0.4 X 0.2 mm, monoclinic, P21/c, a, 1063.3(2) pm, b, 1365.8(3) pm, c, 2140.2(5) pm, β, 104.335(3)°, V, 3.0113(10) nm3; Z, 4, ρcalcd
    • -3 residual densities. CCDC-687124 (2), -687125 (3), -687126 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 40
    • 85163236907 scopus 로고    scopus 로고
    • C. Strohmann, T. Seibel, K. Strohfeldt, Angew. Chem. 2003, 115, 4669; Angew. Chem. Int. Ed. 2003, 42, 4531.
    • C. Strohmann, T. Seibel, K. Strohfeldt, Angew. Chem. 2003, 115, 4669; Angew. Chem. Int. Ed. 2003, 42, 4531.
  • 46
    • 85163240440 scopus 로고    scopus 로고
    • Because of the high reactivity of the compounds, the values determined deviate considerably from the calculated numbers. Moreover, compounds 2-4 are adducts, which may lose donor base molecules during the sample preparation routines.
    • Because of the high reactivity of the compounds, the values determined deviate considerably from the calculated numbers. Moreover, compounds 2-4 are adducts, which may lose donor base molecules during the sample preparation routines.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.