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Single-crystal structural analysis of 2-4: The data sets were collected on a Bruker Smart Apex II with a D8 goniometer (2, 3) or a Bruker TXS rotating anode with INCOATEC Mo-mirror optics, Apex II detector and D8 goniometer (4) from oil-coated, shock-cooled crystals[12, Mo-Kα λ, 71.073 pm, The integration was performed with SAINT V7.34A [V7.46A (3, which was followed by an empirical absorption correction with SADABS-2004/1 [SADABS-2007/5(3, The structures were solved by direct methods and refined with SHELXL against F2.[26] 2: C20H54Li 2N4Si2, M, 420.74 gmol-1, crystal size 0.5 X 0.4 X 0.2 mm, monoclinic, P21/c, a, 1063.3(2) pm, b, 1365.8(3) pm, c, 2140.2(5) pm, β, 104.335(3)°, V, 3.0113(10) nm3; Z, 4, ρcalcd
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Because of the high reactivity of the compounds, the values determined deviate considerably from the calculated numbers. Moreover, compounds 2-4 are adducts, which may lose donor base molecules during the sample preparation routines.
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Because of the high reactivity of the compounds, the values determined deviate considerably from the calculated numbers. Moreover, compounds 2-4 are adducts, which may lose donor base molecules during the sample preparation routines.
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