Direct proline catalyzed asymmetric α-aminooxylation of aldehydes

Tetrahedron Letters

Volumn 44, Issue 45, 2003, Pages 8293-8296

  Hayashi, Yujiro ^a   Yamaguchi, Junichiro ^a   Hibino, Kazuhiro ^a   Shoji, Mitsuru ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Asymmetric reaction; Catalytic reaction; Organocatalyst; Proline; aminooxylation

Indexed keywords

ALDEHYDE DERIVATIVE; NITROSOBENZENE; OXYGEN; PROLINE;

ALPHA AMINOOXYLATION; ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; ENANTIOSELECTIVITY; QUANTUM YIELD;

EID: 0141957357     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.09.057     Document Type: Article

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35. 4. Purification by column chromatography with silica gel (AcOEt/hexane=1/10-1/3) afforded aminooxy aldehyde (83.5 mg, 0.5 mmol) quantitatively.