Synthesis of trinuclear osmium polyhydrido clusters [{(C5Me 5)Os}3(μ;-H)6]+ and {(C 5Me5)Os}3(μ-H)3(μ3- H)2 and comparison with the ruthenium analogues

Organometallics

Volumn 27, Issue 16, 2008, Pages 4248-4253

  Kameo, Hajime ^a   Suzuki, Hiroharu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DINUCLEAR; SYNTHESIS OF; TETRAHYDRIDE COMPLEX;

CHLORINE COMPOUNDS;

EID: 51049088391     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8003866     Document Type: Article

References (45)

1. (a) Adams, R. D., Cotton, F. A., Eds. Catalysis by Di- and Polynuclear Metal Cluster Complexes; Wiley-VCH: New York, 1998.
2. (b) Gates, B. C.; Guzei, L. ; Knozinger, V. H., Eds. Metal Clusters in Catalysis; Elsevier: Amsterdam, 1986.
3. (c) Süss-flnk, G.; Meister, G. In Advances in Organometallic Chemistry, Vol. 35; Cotton, F. A., Wilkinson, G., Murillo, C. A., Bochmann, M., Eds.; John Weiley & Sons, Inc.: New York, 1999; pp 41-134.
4. (d) Deeming, A. J. In Advances in Organometallic Chemistry, Vol. 26; Cotton, F. A., Wilkinson, G., Murillo, C. A., Bochmann, M., Eds.; John Wiley & Sons, Inc.: New York, 1999; pp 1-96.
5. (e) Hogarth, G. In Comprehensive Organometallic Chemistry III, Vol. 6; Crabtree, R. H., Mingos, D. J. P., Eds.; Elsevier: Oxford, UK, 2007; Chapter 6.06.
6. (f) Wilton-Ely, J. D. In Comprehensive Organometallic Chemistry III, Vol. 6; Crabtree, R. H., Mingos, D. J. P., Eds.; Elsevier: Oxford, UK, 2007; Chapter 6.17.
7. (a) Suzuki, H.; Kakigano, T.; Tada, K.; Igarashi, M.; Matsubara, K.; Inagaki, A.; Oshima, M.; Takao, T. Bull. Chem. Soc. Jpn. 2005, 78, 67.
8. (b) Suzuki, H. Eur. J. Inorg. Chem. 2002, 1009.
9. Ito, Y. Master Thesis, Tokyo Institute of Technology, 1999. To be published.
10. (a) Suzuki, H.; Omori, H.; Lee, D. H.; Yoshida, Y.; Fukushima, M.; Tanaka, M.; Moro.oka, Y. Organometallics 1994, 13, 1129.
11. (b) Inagaki, A.; Takaya, Y.; Takemori, T.; Suzuki, H.; Tanaka, M.; Haga, M. J. Am. Chem. Soc. 1997, 119, 625.
12. (c) Matsubara, K.; Okamura, R.; Tanaka, M.; Suzuki, H. J. Am. Chem. Soc. 1998, 120, 1108.
13. (d) Inagaki, A.; Takemori, T.; Tanaka, M.; Suzuki, H. Angew. Chem., Int. Ed. 2000, 39, 404.
14. (e) Matsubara, K.; Inagaki, A.; Tanaka, M.; Suzuki, H. J.. Am. Chem. Soc. 1999, 121, 7421.
15. (f) Takemori, T.; Inagaki, A.; Suzuki, H. J. Am. Chem. Soc. 2001, 123, 1762.
16. (g) Ohashi, M.; Matsubara, K.; Iizuka, T.; Suzuki, H. Angew. Chem., Int. Ed. 2003, 42, 937.
17. (h) Nakajima, Y.; Suzuki, H. Organometallics 2003, 22, 959.
18. (i) Inagaki, A.; Musaev, G.; Takemori, T.; Suzuki, H.; Morokuma, K. Organometallics 2003, 22, 1718.
19. (j) Khoroshun, D. V.; Inagaki, A.; Suzuki, H.; Vyboishchikov, S. F.; Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 2003, 125, 9910.
20. (k) Nakajima, Y.; Kameo, H.; Suzuki, H. Angew. Chem., Int. Ed. 2006, 45, 950.
21. (l) Kawashima, T; Takao, T; Suzuki, H. Angew.Chem., Int. Ed. 2006, 45, 7615.
22. (m) Moriya, M.; Takao, T.; Suzuki, H. Organometallics 2007, 26, 6329.
23. (n) Kameo, H.; Nakajima, Y.; Suzuki, H. Eur. J. Inorg. Chem. 2007, 1793.
24. (o) Ohki, Y.; Suzuki, H. Angew. Chem., Int. Ed. 2002, 41, 2994.
25. (a) Koga, N.; Morokuma, K. J. Mol. Struct. 1993, 300, 181.
26. (b) Riehl, J.-F.; Koga, N.; Morokuma, K. Organometallics 1994, 13, 4765.
27. (c) Tussupbayev, S.; Vyboishchikov, S. F. Organometallics 2007, 26, 56.
28. (d) Tsipis, A. C.; Kefalidis, C. E.; Tsipis, C. A. J. Am. Chem. Soc 2007, 129, 13905.
29. (a) Gross, C. L.; Wilson, S. R.; Girolami, G. S. J. Am. Chem. Soc. 1994, 116, 10294.
30. (b) Gross, C. L.; Girolami, G. S. Organometallics 2007, 26, 160.
31. 5).
32. (a) Ohki, Y.; Suzuki, H. Angew. Chem., Int. Ed. 2000, 39, 3120.
33. (b) Shima, T.; Suzuki, H. Organometallics 2005, 24, 3939.
34. (c) Shima, T.; Suzuki, H. Organometallics 2000, 19, 2420.
35. + (5) has five bridging hydrides. This may be reflected in the reactivity. One of the ruthenium atoms in I is probably highly unsaturated, and protonation would readily proceed at this site.
36. Ito, J.; Shima, T.; Suzuki, H. Organometallics 2004, 23, 2447.
37. (a) Hamilton, D. G.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 4126.
38. (b) Kubas, G. J. Metal Dihydrogen and σ-Bond Complexes; Kluwer Academic/Plenum Publishers: New York, 2001.
39. PROCESS-AUTO, Automatic Data Acquisition and Processing Package for Imaging Plate Diffractometer; Rigaku Corporation: Tokyo (Japan), 1998.
40. Sheldrick, G. M. SHELX-97, Program for Crystal Structure Determination; University of Göttingen: Göttingen (Germany), 1997.
41. + exhibited no imaginary frequency.
42. Pople, J. A.; et al. Gaussian 03, Revision D.02; Gaussian, Inc.: Wallingford, CT, 2004.
43. (a) Becke, A. D. Phys. Rev. A 1988, 38, 3098.
44. (b) Becke, A. D. J. Chem. Phys. 1983, 98, 5648.
45. (c) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.