[{(η5-C5Me5)Fe}2(μ-H)4]: A novel dinuclear iron tetrahydrido complex

Angewandte Chemie - International Edition

Volumn 39, Issue 17, 2000, Pages 3120-3122

  Ohki, Yasuhiro ^a   Suzuki, Hiroharu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

C H activation; Dinuclear complexes; Hydrido complexes; Iron; Si H activation

Indexed keywords

IRON DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENTHALPY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY DIFFRACTION;

EID: 0034283187     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000901)39:17<3120::AID-ANIE3120>3.0.CO;2-K     Document Type: Article

References (42)

1. a) G. Süss-Fink, G. Meister, Adv. Organomet. Chem. 1993, 35, 41;
2. b) Metal Clusters in Catalysis (Ed.: B.C. Gates, L. Guzci, V. H. Knozinger), Elsevier, Amsterdam, 1986;
3. c) Catalysis by Di- and Polynuclear Metal Cluster Complexes (Ed.: R. D. Adams, F. A. Cotton), WILEY-VCH. New York. 1998;
4. d) P. Braunstein, J. Rose in Comprehensive Organometallic Chemistry, Vol. 10, (Eds.: E. W. Abel, F.G. A. Stone, G. Wilkinson), 2nd ed., Pergamon, Oxford. 1995, Chapter 7, pp. 351-385;
5. e) P. Braunstein, J. Rose in Metal Clusters in Chemistry (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby). Wiley-VCH, Weinheim, 1999, pp 616-677.
6. a) H. Suzuki, H. Omori, Y. Moro-oka, Organometallics 1988, 7, 2579;
7. b) H. Omori, H. Suzuki, Y. Moro-oka, Organometallics 1989, 8, 1576;
8. c) H. Omori, H. Suzuki, Y. Take, Y. Moro-oka. Organometallics 1989, 8, 2270;
9. d) H. Suzuki, T. Takao, M. Tanaka, Y. Moro-oka, J. Chem. Soc. Chem. Commun. 1992, 476;
10. e) H. Suzuki, H. Omori, D. H. Lee, Y. Yoshida, M. Fukushima, M. Tanaka, Y. Moro-oka, Organometallics 1994, 13, 1129;
11. f) T. Takao, H. Suzuki, M. Tanaka, Organometallics 1994, 13, 2554;
12. g) H. Suzuki, Y. Takaya, T. Takemori, M. Tanaka, J. Am. Chem. Soc. 1994, 116, 10779;
13. h) T. Takao, S. Yoshida, H. Suzuki, M. Tanaka, Organometallics 1995, 14, 3855;
14. i) K. Tada, M. Oishi, H. Suzuki, M. Tanaka, Organometallics 1996, 15, 2422;
15. j) A. Inagaki, Y. Takaya, T. Takemori, H. Suzuki, M. Tanaka, M. Haga, J. Am. Chem. Soc. 1997, 119, 625;
16. k) K. Matsubara, R. Okamura, M. Tanaka, H. Suzuki, J. Am. Chem. Soc. 1998, 120, 1108;
17. l) K. Matsuhara, A. Inagaki, M. Tanaka, H. Suzuki, J. Am. Chem. Soc. 1999, 121, 7421;
18. m) A. Inagaki, T. Takemori, M. Tanaka, H. Suzuki, Angew. Chem. 2000, 112, 411; Angew. Chem. Int. Ed. 2000, 39, 404.
19. m) A. Inagaki, T. Takemori, M. Tanaka, H. Suzuki, Angew. Chem. 2000, 112, 411; Angew. Chem. Int. Ed. 2000, 39, 404.
20. K. Jonas, P. Klusmann, R. Goddard, Z. Naturforsch. B 1995, 50, 394.
21. R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789, and references therein.
22. R. H. Crabtree, Angew. Chem. 1993, 105, 828; Angew. Chem. Int. Ed. Engl. 1993, 32, 789, and references therein.
23. w = 0.026, for 167 parameters, b) Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-142856 (4), CCDC-142858 (5), and CCDC-142857 (6). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).
24. (6] N. Koga, K. Morokuma, J. Mol. Struct. (THEOCHEM) 1993,300,181.
25. w = 0.044.[b]
26. a) H. Tobita, Y. Kawano, M. Shimoi, H. Ogino, Chem. Lett. 1987, 2247;
27. b) S. G. Anema, G. C. Barris, K. M. Mackay, B. K. Nicholson, J. Organomet. Chem. 1988, 350, 207;
28. c) S. G. Anema, K.M. Mackay, B. K. Nicholson, M. V. Tiel, Organometallics 1990, 9, 2436;
29. d) N. I. Kirillova, A. I. Gusev, O. N. Kalinina, O. B. Afanasova, E. A. Chernyshev, Metalloorg. Khim. 1991, 4, 773;
30. e) K. Ueno, N. Hamashima, M. Shimoi, H. Ogino, Organometallics 1991, 10, 959;
31. f) H. Tobita, I. Shinagawa, S. Ohnuki, M. Abe, H. Izumi, H. Ogino, J. Organomet. Chem. 1994, 473, 187;
32. g) H. Tobita, H. Izumi, S. Ohnuki, M. C. Ellerby, M. Kikuchi, S. Inomata, H. Ogino, J. Am. Chem. Soc. 1995, 117, 7013;
33. h) R. S. Simons, C. A. Tessier, Acta Crystallogr. Sect. C 1995, 51, 1997;
34. i) R. S. Simons, C. A. Tessier, Organometallics 1996, 15, 2604;
35. j) P. Braunstein, M. Knorr, C. Stern, Coord. Chem. Rev. 1998, 178-180, 903-965.
36. w = 0.037.[b]
37. For cyclopentadienyliron complexes, see: a) H. R. Allcock, P.P. Greigger, L. J. Wagner, M. Y. Bernheim, Inorg. Chem. 1981, 20, 716; b) B. Deppisch, S. Schafer, Acta Crystallogr. Sect. C 1983, 39, 975; c) H. G. Raubenheimer, F. Scott, S. Cronje, P. H. Van Rooyan, J. Chem. Soc. Dalton Trans. 1992, 1859; d) C. Klasen, G. Effinger, S. Schmidt, I.-P. Lorenz, Z. Naturforsch. B 1993, 48, 705; e) I.-P. Lorenz, W. Pohl, K. Polborn, Chem. Ber. 1996, 129, 11.
38. For cyclopentadienyliron complexes, see: a) H. R. Allcock, P.P. Greigger, L. J. Wagner, M. Y. Bernheim, Inorg. Chem. 1981, 20, 716; b) B. Deppisch, S. Schafer, Acta Crystallogr. Sect. C 1983, 39, 975; c) H. G. Raubenheimer, F. Scott, S. Cronje, P. H. Van Rooyan, J. Chem. Soc. Dalton Trans. 1992, 1859; d) C. Klasen, G. Effinger, S. Schmidt, I.-P. Lorenz, Z. Naturforsch. B 1993, 48, 705; e) I.-P. Lorenz, W. Pohl, K. Polborn, Chem. Ber. 1996, 129, 11.
39. For cyclopentadienyliron complexes, see: a) H. R. Allcock, P.P. Greigger, L. J. Wagner, M. Y. Bernheim, Inorg. Chem. 1981, 20, 716; b) B. Deppisch, S. Schafer, Acta Crystallogr. Sect. C 1983, 39, 975; c) H. G. Raubenheimer, F. Scott, S. Cronje, P. H. Van Rooyan, J. Chem. Soc. Dalton Trans. 1992, 1859; d) C. Klasen, G. Effinger, S. Schmidt, I.-P. Lorenz, Z. Naturforsch. B 1993, 48, 705; e) I.-P. Lorenz, W. Pohl, K. Polborn, Chem. Ber. 1996, 129, 11.
40. For cyclopentadienyliron complexes, see: a) H. R. Allcock, P.P. Greigger, L. J. Wagner, M. Y. Bernheim, Inorg. Chem. 1981, 20, 716; b) B. Deppisch, S. Schafer, Acta Crystallogr. Sect. C 1983, 39, 975; c) H. G. Raubenheimer, F. Scott, S. Cronje, P. H. Van Rooyan, J. Chem. Soc. Dalton Trans. 1992, 1859; d) C. Klasen, G. Effinger, S. Schmidt, I.-P. Lorenz, Z. Naturforsch. B 1993, 48, 705; e) I.-P. Lorenz, W. Pohl, K. Polborn, Chem. Ber. 1996, 129, 11.
41. For cyclopentadienyliron complexes, see: a) H. R. Allcock, P.P. Greigger, L. J. Wagner, M. Y. Bernheim, Inorg. Chem. 1981, 20, 716; b) B. Deppisch, S. Schafer, Acta Crystallogr. Sect. C 1983, 39, 975; c) H. G. Raubenheimer, F. Scott, S. Cronje, P. H. Van Rooyan, J. Chem. Soc. Dalton Trans. 1992, 1859; d) C. Klasen, G. Effinger, S. Schmidt, I.-P. Lorenz, Z. Naturforsch. B 1993, 48, 705; e) I.-P. Lorenz, W. Pohl, K. Polborn, Chem. Ber. 1996, 129, 11.
42. -1). T. Takao, S. Yoshida, H. Suzuki, unpublished results.