Hydrogen-bonding network in new scorpionate-type ligand composed of pyridine/pyrrole hybrid and anion-binding behavior of the corresponding rhodium complexes in alkyne cyclotrimerization reaction

Journal of Organometallic Chemistry

Volumn 693, Issue 19, 2008, Pages 3141-3150

  Toganoh, Motoki ^a   Harada, Naoyuki ^a   Furuta, Hiroyuki ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

Anion binding; Cyclotrimerization; Rhodium; Scorpionate ligand

Indexed keywords

ACETYLENE; BONDING; CATALYST ACTIVITY; CHLORINE COMPOUNDS; DYES; HYDROGEN; HYDROGEN BONDS; IONS; LIGANDS; METALS; METHANE; NEGATIVE IONS; NONMETALS; RHODIUM;

ANION-BINDING; BINDING BEHAVIORS; CATALYTIC ACTIVITIES; COUNTER ANIONS; CYCLOTRIMERIZATION; CYCLOTRIMERIZATION REACTIONS; ELECTRON-DONATING; HYDROGEN BONDINGS; HYDROGEN-BONDING NETWORKS; METAL CENTERS; RHODIUM COMPLEXES; RHODIUM III COMPLEXES; SCORPIONATE LIGAND; SOLID STATES; X-RAY CRYSTALLOGRAPHIC ANALYSIS;

RHODIUM COMPOUNDS;

EID: 50449096431     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.07.005     Document Type: Article

References (53)

1. Trofimenko S. J. Am. Chem. Soc. 88 (1966) 1842
2. Trofimenko S. Chem. Rev. 93 (1993) 943
3. Roger D.L. Coord. Chem. Rev. 147 (1996) 571
4. Etienne M. Coord. Chem. Rev. 156 (1997) 201
5. Janiak C. Coord. Chem. Rev. 163 (1997) 107
6. Akita M. J. Organomet. Chem. 689 (2004) 4540
7. Akita M., and Hikichi S. Bull. Chem. Soc. Jpn. 75 (2002) 1657
8. Toganoh M., Ishizuka T., and Furuta H. Chem. Commun. (2004) 2464
9. Toganoh M., and Furuta H. Chem. Lett. (2005) 1034
10. Toganoh M., Ikeda S., and Furuta H. Chem. Commun. (2005) 4589
11. Toganoh M., Ikeda S., and Furuta H. Inorg. Chem. 46 (2007) 10003
12. Toganoh M., Fujino K., Ikeda S., and Furuta H. Tetrahedron Lett. 49 (2008) 1488
13. Otero A., Fernández-Baeza J., Antiñolo A., Tejeda J., and Lara-Sánchez A. Dalton Trans. (2004) 1499
14. Pettinari C., Cingolani A., Gioia Lobbia G., Marchetti F., Martini D., Pellei M., Pettinari R., and Santini C. Polyhedron 23 (2004) 451
15. Janiak C. J. Chem. Soc., Chem. Commun. (1994) 545
16. Reglinski J., Garner M., Cassidy I.D., Slavin P.A., Spicer M.D., and Armstrong D.R. J. Chem. Soc., Dalton Trans. (1999) 2119
17. Kläui W., Berghahn M., Frank W., Reiß G.J., Schönherr T., Rheinwald G., and Lang H. Eur. J. Inorg. Chem. (2003) 2059
18. Chiou S.-J., Ge P., Riordan C.G., Liable-Sands L.M., and Rheingold A.L. Chem. Commun. (1999) 159
19. Bailey P.J., Lanfranchi M., Marchiò L., and Parsons S. Inorg. Chem. 40 (2001) 5030
20. Careri M., Elviri L., Lanfranchi M., Marchiò L., Mora C., and Pellinghelli M.A. Inrog. Chem. 42 (2003) 2109
21. Trofimenko S. J. Am. Chem. Soc. 92 (1970) 5118
22. Joshi V.S., Kale V.K., Sathe K.M., Sarkar A., Tavale S.S., and Soresh C.G. Organometallics 10 (1991) 2898
23. Kimblin C., Murphy V.J., and Parkin G. J. Chem. Soc., Chem. Commun. (1996) 235
24. Richburg L.M., Farouq J.A., Incarvito C.D., Rheingold A.L., and Rabinovich D. Polyhedron 19 (2000) 1815
25. Sessler J.L., Camiolo S., and Gale P.A. Coord. Chem. Rev. 240 (2003) 17
26. Maeda H. Eur. J. Org. Chem. (2007) 5313
27. Maeda H., Ishikawa Y., Matsuda T., Osuka A., and Furuta H. J. Am. Chem. Soc. 125 (2003) 11822
28. Maeda H., Morimoto T., Osuka A., and Furuta H. Chem. Asian J. 1 (2006) 832
29. Xie Y., Morimoto T., and Furuta H. Angew. Chem., Int. Ed. 45 (2006) 6907
30. Maeda H., Osuka A., and Furuta H. Supramol. Chem. 15 (2003) 447
31. Morimoto T., and Furuta H. Supramol. Chem. 19 (2007) 493
32. Macchioni A. Chem. Rev. 105 (2005) 2039
33. Duckmanton P.A., Blake A.J., and Love J.B. Inorg. Chem. 44 (2005) 7708
34. van den Broeke J., de Wolf E., Deelman B.-J., and van Koten G. Adv. Synth. Catal. 345 (2003) 625
35. Burling S., Field L.D., Messerle B.A., and Turner P. Organometallics 23 (2004) 1714
36. Terai H., Takaya H., and Naota T. Tetrahedron Lett. 47 (2006) 1705
37. Tong X., Zhang Z., and Zhang X. J. Am. Chem. Soc. 125 (2003) 6370
38. Tanaka K., and Fu G.C. J. Am. Chem. Soc. 123 (2001) 11492
39. Ono Y., and Furuta H. Chem. Lett. 35 (2006) 750
40. Ito F., Nagai T., Ono Y., Yamaguchi K., Furuta H., and Nagamura T. Chem. Phys. Lett. 435 (2007) 283
41. Borrini A., Diversi P., Ingrosso G., Lucherini A., and Serra G. J. Mol. Catal. 30 (1985) 181
42. Chen W., and Cava M.P. Tetrahedron Lett. 28 (1987) 6025
43. Chen W., Stephenson E.K., Cava M.P., and Jackson Y.A. Org. Synth. 70 (1992) 151
44. Hasan I., Marinelli E.R., Lin L.C., Fowler F.W., and Levy A.B. J. Org. Chem. 41 (1976) 3668
45. Cox E.D., and Cook J.M. Chem. Rev. 95 (1995) 1797
46. Mayer J.P., Bankaitis-Davis D., Zhang J., Beaton G., Bjergarde K., Andersen C.M., Goodman B.A., and Herrera C.J. Tetrahedron Lett. 37 (1996) 5633
47. Yeh W.-B., Lin M.-J., and Sun C.-M. Tetrahedron Lett. 44 (2003) 4923
48. Bringmann G., Feineis D., God R., Maksimenka K., Mühlbacher J., Messer K., Münchbach M., Gulden K.-P., Peters E.-M., and Peters K. Tetrahedron 60 (2004) 8143
49. Inter or intramolecular hydrogen bondings could be formed in 1 and 2 in solution and cause the considerable low-field shifts from a free pyrrolic NH moiety (δ ∼ 8.2 ppm).
50. In the case of 8a-Cl, significant amount of a bis-Rh(I) complex of 1a was obtained after treatment with base and hence the reaction was not completely reversible.
51. Orian L., van Stralen J.N.P., and Bickelhaupt F.M. Organometallics 26 (2007) 3816
52. Kirchner K., Calhorda M.J., Schmid R., and Veiros L.F. J. Am. Chem. Soc. 125 (2003) 11721
53. Sheldrick G.M. Program for the Solution of Crystal Structures (1997), University of Göttingen, Göttingen, Germany