PtII-catalyzed synthesis of 9-oxabicyclo[3.3.1]nona-2,6-dienes from 2-alkynyl-1-carbonylbenzenes and allylsilanes by an allylation/annulation cascade

Angewandte Chemie - International Edition

Volumn 47, Issue 27, 2008, Pages 5063-5066

  Bhunia, Sabyasachi ^a   Wang, Kuo Chang ^a   Liu, Rai Shung ^a  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

Author keywords

Allylation; Annulation; Oxygen heterocycles; Platinum

Indexed keywords

ACETYLENE; CHEMICAL REACTIONS; SYNTHESIS (CHEMICAL);

ALLYL SILANES; ALLYLATION; ANNULATION; CARBONYL GROUPS; CATALYTIC SYNTHESIS; CHEMICAL EQUATIONS; HYDROALKOXYLATION; OXYGEN HETEROCYCLES; REACTION SEQUENCES;

PLATINUM;

ALKYNE; ALLYL COMPOUND; BENZENE DERIVATIVE; BICYCLO COMPOUND; HETEROCYCLIC COMPOUND; OXYGEN; PLATINUM; SILANE DERIVATIVE; WATER;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY;

ALKYNES; ALLYL COMPOUNDS; BENZENE DERIVATIVES; BICYCLO COMPOUNDS; CATALYSIS; HETEROCYCLIC COMPOUNDS; MOLECULAR STRUCTURE; OXYGEN; PLATINUM; SILANES; WATER;

EID: 49849093426     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200800826     Document Type: Article

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39. [11] rather than by the mechanism proposed in Scheme 2. We thank one reviewer for this valuable comment.