Intramolecular Michael-type additions to vinyl bissulfoxides: Enantioselective synthesis of chiral aldehydes

Synthesis

Volumn , Issue 15, 2008, Pages 2476-2487

  Gehring, Timo ^a   Podlech, Joachim ^a   Rothenberger, Alexander ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Nucleophilic additions; Stereoelectronic effects; Sulfoxides; Thioacetals; Umpolung

Indexed keywords

ALDEHYDES; ARSENIC COMPOUNDS; CHLORINE COMPOUNDS; ORGANIC COMPOUNDS;

ALKYLIDENE; CARBALDEHYDES; CHIRAL ALDEHYDES; CYCLIC SUBSTRATES; DIASTEREOSELECTIVE; ENANTIO-SELECTIVE SYNTHESIS; ENANTIOMERICALLY PURE COMPOUNDS; NUCLEOPHILIC ADDITIONS; STEREOELECTRONIC EFFECTS; SULFOXIDES; TARGET MOLECULES; TETRAHYDROPYRAN; THIOACETALS; UMPOLUNG;

COMPLEXATION;

(1,3 DIOXO[1,3]DITHIAN 2 YL)TETRAHYDROPYRAN; ([1,3]DITHIAN 2 YL)TETRAHYDROPYRAN; 2 (1,3 DIOXO[1,3]DITHIAN 2 YL)TETRAHYDROFURAN; 2 (1,3 DIOXO[1,3]DITHIOLAN 2 YL)TETRAHYDROFURAN; 2 (1,3 DIOXO[1,3]DITHIOLAN 2 YL)TETRAHYDROPYRAN; 2 ([1,3]DITHIAN 2 YL)TETRAHYRDOPYRAN; 5 (1,3 DIOXO[1,3]DITHIAN 2 YLIDENE)PENTAN 1 OL; 5 ([1,3]DITHIAN 2 YLIDENE)PENTAN 1 OL; ALDEHYDE DERIVATIVE; BENZYL 2 (1,3 DIOXO[1,3]DITHIOLAN 2 YL)PIPERIDINE 1 CARBOXYLATE; BENZYL 2 FORMYLPIPERIDINE 1 CARBOXYLATE; BENZYL 2(1,3 DIOXO[1,3]DITHIAN 2 YL)PIPERIDINE 1 CARBOXYLATE; BENZYL 2([1,3]DITHIAN 2 YL)PIPERIDINE 1 CARBOXYLATE; KETENE DERIVATIVE; TARTARIC ACID; TERT BUTYL (5 [1,3]DITHIAN 2 YLIDENEPENTYLOXY)DIMETHYLSILANE; TERT BUTYL 5 ([1,3]DITHIOLAN 2 YLIDENE)PENTYLCARBAMATE; TERT BUTYL [5 (1,3 DIOXO[1,3]DITHIAN 2 YLIDENE)PENTYL]CARBAMATE; TERT BUTYL [5 (1,3 DIOXO[1,3]DITHIAN 2 YLIDENE)PENTYLOXY]DIMETHYLSILANE; TERT BUTYL [5 (1,3 DIOXO[1,3]DITHIOLAN 2 YLIDENE)PENTYL]CARBAMATE; TETRAHYDROPAN 2 CARBALDEHYDE; TETRAHYDROPYRAN 2 CARBALDEHYDE; TETRAHYDROPYRAN DERIVATIVE; VINYL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; HYDROLYSIS; MICHAEL ADDITION; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 49649128371     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067176     Document Type: Article

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