SCOPUS 정보 검색 플랫폼

Volumn , Issue 15, 2008, Pages 2323-2326

A concise enantioselective strategy to (+)-(R)-goniothalamin and (+)-(R)-goniothalamin oxide by employing hydrolytic kinetic resolution and ring-closing metathesis as key steps

(3) Bose, D Subhas a Reddy, A V Narsimha a Srikanth, Bingi a

a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY (India)

Author keywords

Goniothalamin; Jacobsen's epoxidation; Metathesis; Natural products; Styryl lactones

Indexed keywords

BIOLOGICAL ACTIVITIES; DIASTEREOMERIC EXCESS; ENANTIOSELECTIVE; GONIOTHALAMIN; HIGH YIELD; HYDROLYTIC KINETIC RESOLUTION; JACOBSEN'S EPOXIDATION; METATHESIS; NATURAL PRODUCTS; RING-CLOSING METATHESIS; STYRYL LACTONES;

RAW MATERIALS;

GONIOTHALAMIN; GONIOTHALAMIN OXIDE; LARVICIDAL AGENT;

ANTINEOPLASTIC ACTIVITY; APOPTOSIS; ARTICLE; CONTROLLED STUDY; CYTOTOXICITY; DIASTEREOISOMER; DRUG STRUCTURE; ENANTIOSELECTIVITY; EPOXIDATION; HUMAN; HUMAN CELL; HYDROLYSIS KINETICS; IN VITRO STUDY; IN VIVO STUDY; NONHUMAN; RACEMIZATION; RAT; RING CLOSING METATHESIS;

EID: 49649123062 PISSN: 00397881 EISSN: None Source Type: Journal
DOI: 10.1055/s-2008-1067175 Document Type: Article

Times cited : (17)

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- + + H], 183.1 (100), 155.2 (66), 130.1 (41).

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58
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- R)-Goniothalamin Oxide (2, Mp 90-92°C (Lit. 25b 90-94°C, α]D +100.1 (c 0.88, CHCl3, Lit.25b [α]D +100.7 (c 0.70, CHCl3, IR (KBr, 3055, 3025, 2928, 1720, 1605, 1245, 1035, 808 cm-1. 1H NMR (300 MHz, CDCl3, δ, 2.59 (m, 2 H, 3.28 (dd, J6,5, 5.6 Hz, J6,7, 2.0 Hz, 1 H, 3.91 (d, J7,6, 1.8 Hz, 1 H, 4.45 (dt, J5,4, 9.4 Hz, J5,4¢ and 6, 5.5 Hz, 1 H, 6.07 (dt, J2,3, 9.7 Hz, J2,4, 2.0 Hz, 1 H, 6.95 (m, 1 H, 7.32-7.39 (m, 5 H, 13C NMR (75 MHz, CDCl 3, δ, 26.3, 57.5, 61.9, 77.2, 121.6, 125.5, 128.7, 135.5, 144.4, 164.0. MS (APCI, m/z, 217.0 (100, M, H, 199.0 (45, 171.1 (83, 143.1 (45, 139.0 (32, 105.0 (31, 91.0 31, HRMS: m/z
- 3: 239.0684; found: 239.0682.

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