Ultrafast X-ray solution scattering reveals an unknown reaction intermediate in the photolysis of [Ru3(CO)12]

Angewandte Chemie - International Edition

Volumn 47, Issue 30, 2008, Pages 5550-5553

  Kong, Qingyu ^b   Lee, Jae Hyuk ^a   Plech, Anton ^c   Wulff, Michael ^b   Ihee, Hyotcherl ^a   Koch, Michel H J ^d  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^c UNIVERSITY OF KONSTANZ   (Germany)

^d EUROPEAN MOLECULAR BIOLOGY LABORATORY   (Germany)

Author keywords

Carbonyl ligands; Photochemistry; Reaction mechanisms; Time resolved spectroscopy; X ray scattering

Indexed keywords

PHOTOLYSIS;

CARBONYL LIGANDS; PHOTOCHEMISTRY; REACTION MECHANISMS; TIME-RESOLVED SPECTROSCOPY; X-RAY SCATTERING;

SCATTERING;

LIGAND; RUTHENIUM DERIVATIVE;

ARTICLE; CHEMISTRY; HYDROLYSIS; METHODOLOGY; PHOTOCHEMISTRY; RADIATION SCATTERING; SPECTROSCOPY;

HYDROLYSIS; LIGANDS; PHOTOCHEMISTRY; RUTHENIUM COMPOUNDS; SCATTERING, RADIATION; SPECTRUM ANALYSIS;

EID: 49649111912     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801153     Document Type: Article

References (24)

1. J. G. Bentsen, M. S. Wrighton, J. Am. Chem. Soc. 1987, 109, 4530.
2. B. F. G. Johnson, J. Lewis, M. V. Twigg, J. Organomet. Chem. 1974, 67, C75.
3. M. G. Richmond, Coord. Chem. Rev. 2004, 248, 881.
4. Y. M. Wuu, J. G. Bentsen, C. G. Brinkley, M. S. Wrighton, Inorg. Chem. 1987, 26, 530.
5. J. G. Bentsen, M. S. Wrighton, J. Am. Chem. Soc. 1987, 109, 4518.
6. M. F. Desrosiers, P. C. Ford, Organometallics 1982, 1, 1715.
7. J. Malito, S. Markiewitz, A. Poe, Inorg. Chem. 1982, 21, 4335.
8. J. L. Graff, R. D. Sanner, M. S. Wrighton, J. Am. Chem. Soc. 1979, 101, 273.
9. F. W. Grevels, J. G. A. Reuvers, J. Takats, J. Am. Chem. Soc. 1981, 103, 4069.
10. M. F. Desrosiers, D. A. Wink, R. Trautman, A. E. Friedman, P. C. Ford, J. Am. Chem. Soc. 1986, 108, 1917.
11. F. W. Grevels, W. E. Klotzbucher, J. Schrickel, K. Schaffner, J. Am. Chem. Soc. 1994, 116, 6229.
12. E. A. Glascoe, M. F. Kling, J. E. Shanoski, C. B. Harris, Organometallics 2006, 25, 775.
13. A. Plech, M. Wulff, S. Bratos, F. Mirloup, R. Vuilleumier, F. Schotte, P. A. Anfinrud, Phys. Rev. Lett. 2004, 92, 125505.
14. H. Ihee, M. Lorenc, T. K. Kim, Q. Y. Kong, M. Cammarata, J. H. Lee, S. Bratos, M. Wulff, Science 2005, 309, 1223.
15. T. K. Kim, M. Lorenc, J. H. Lee, M. Lo Russo, J. Kim, M. Cammarata, Q. Kong, S. Noel, A. Plech, M. Wulff, H. Ihee, Proc. Natl. Acad. Sci. USA 2006, 103, 9410.
16. Q. Y. Kong, M. Wulff, J. H. Lee, S. Bratos, H. Ihee, J. Am. Chem. Soc. 2007, 129, 13584.
17. M. Wulff, S. Bratos, A. Plech, R. Vuilleumier, F. Mirloup, M. Lorenc, Q. Kong, H. Ihee, J. Chem. Phys. 2006, 124, 034501.
18. M. Cammarata, M. Lorenc, T. K. Kim, J. H. Lee, Q. Y. Kong, E. Pontecorvo, M. Lo Russo, G. Schirò, A. Cupane, M. Wulff, H. Ihee, J. Chem. Phys. 2006, 124, 124504.
19. E. Hunstock, C. Mealli, M. J. Calhorda, J. Reinhold, Inorg. Chem. 1999, 38, 5053.
20. J. H. Lee, K. H. Kim, T. K. Kim, Y. Lee, H. Ihee, J. Chem. Phys. 2006, 125, 174504.
21. J. Davidsson, J. Poulsen, M. Cammarata, P. Georgiou, R. Wouts, G. Katona, F. Jacobson, A. Plech, M. Wulff, G. Nyman, R. Neutze, Phys. Rev. Lett. 2005, 94, 245503.
22. J. H. Lee, J. Kim, M. Cammarata, Q. Kong, K. H. Kim, J. Choi, T. K. Kim, M. Wulff, H. Ihee, Angew. Chem. 2008, 120, 1063;
23. Angew. Chem. Int. Ed. 2008, 47, 1047.
24. K. J. Gaffney, H. N. Chapman, Science 2007, 316, 1444.