Nature and role of bridged carbonyl intermediates in the ultrafast photoinduced rearrangement of Ru 3(CO) 12

Organometallics

Volumn 25, Issue 3, 2006, Pages 775-784

  Glascoe, Elizabeth A ^a   Kling, Matthias F ^a,b   Shanoski, Jennifer E ^a   Harris, Charles B ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b FOM INSTITUTE AMOLF   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL COMPLEXES; DENSITY FUNCTIONAL THEORY (DFT); TRIMETAL CLUSTERS;

INFRARED SPECTROSCOPY; PHOTOCHEMICAL REACTIONS; PROBABILITY DENSITY FUNCTION; SOLVENTS; ULTRAVIOLET RADIATION;

RUTHENIUM COMPOUNDS;

EID: 33644516343     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050795o     Document Type: Article

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40. The first 50 ps was removed because an early time low-energy shift of the peak made the longer time high-energy shift difficult to determine. The low-energy shift may result from difficulty in fitting the peak at early times because it is vibrationally excited, very broad, and rather weak in amplitude.