Structure-reactivity relationships for β-galactosidase (escherichia coli, lac Z): A second derivative effect on βnuc for addition of alkyl alcohols to an oxocarbenium ion reaction intermediate

Journal of Physical Organic Chemistry

Volumn 21, Issue 7-8, 2008, Pages 531-537

  Richard, John P ^a   Heo, Christina K ^a   Toteva, Maria M ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

Br nsted coefficient; Glycosyl transfer; Nucleophile addition; Structure reactivity effects; Substituent effects

Indexed keywords

ESCHERICHIA COLI; RATE CONSTANTS;

CONSTANT RATIO; GALACTOPYRANOSIDE; GALACTOSIDASE; SECOND DERIVATIVES; STRUCTURE-REACTIVITY RELATIONSHIPS; TRIFLUOROETHANOL (TFE);

ETHANOL;

EID: 46949090316     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1302     Document Type: Conference Paper

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